79825-72-2

Basic information

• Product Name: methyl-d₃ 4-bromobenzoate
• CAS NO: 79825-72-2
• Molecular Weight: 218.023
• Mol File: 79825-72-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl-d₃ 4-bromobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-d₃ 4-bromobenzoate(79825-72-2)
• EPA Substance Registry System: methyl-d₃ 4-bromobenzoate(79825-72-2)

Safety Data

• Hazardous Substances Data: 79825-72-2(Hazardous Substances Data)

Upstream product

• 586-76-5 4-Bromobenzoic acid 
• 23726-00-3 <²H9>trimethylsulphoxonium iodide 
• 811-98-3 d⁽⁴⁾-methanol 
• 57699-28-2 methyl 4-bromophenylglyoxalate 

Relevant articles and documents

Trideuteromethylation Enabled by a Sulfoxonium Metathesis Reaction

A conceptually novel sulfoxonium metathesis reaction between TMSOI and cost-effective DMSO-d6 is developed for the efficient generation of a new trideuteromethylation reagent TDMSOI. The new reagent TDMSOI is produced highly efficiently by simply heating a mixture of TMSOI and DMSO-d6 and directly used for subsequent trideuteromethylation in a "one-pot" operation. The preparative power of the new versatile reagent and the "one-pot" protocol is demonstrated by its use to install the ?CD3 moiety into broad functionalities including phenols, thiophenols, acidic amines, and enolizable methylene units in high yield and at a useful level of deuteration (>87% D).