80137-06-0

Basic information

• Product Name: (CO)3FeC(BrC₆H₄)S(CH₃)SFe(CO)3
• CAS NO: 80137-06-0
• Molecular Weight: 526.936
• Mol File: 80137-06-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (CO)3FeC(BrC₆H₄)S(CH₃)SFe(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)3FeC(BrC₆H₄)S(CH₃)SFe(CO)3(80137-06-0)
• EPA Substance Registry System: (CO)3FeC(BrC₆H₄)S(CH₃)SFe(CO)3(80137-06-0)

Safety Data

• Hazardous Substances Data: 80137-06-0(Hazardous Substances Data)

Upstream product

• 15321-51-4 diiron nonacarbonyl 
• 5969-46-0 methyl 4-bromodithiobenzoate 

Relevant articles and documents

COMPLEXES BINUCLEAIRES DU FER CARBONYLE A LIAISON ?-METAL-CARBONE: SYNTHESE, ETUDE STRUCTURALE ET PROPRIETES

Dithioesters R1C(S)SR2 react with to afford binuclear complexes (CO)3FeC(R1)S(R2)SFe(CO)3 (I) in which the organic ligand gives six electrons to the Fe2(CO)6 skeleton.Spectroscopic data show the existence of a carbon-iron ? bond with creation of a chiral center.This is confirmed by single-crystal X-ray structure determination of complex Ig (R1=C4H3S, R2=Me).This structure shows that coordination imposes important geometrical constraints. 13C NMR studies reveal a temperature dependant dynamic behaviour for complexes I in solution.The carbonyl fluxionality occurs around each metal atom independently.Electrophilic substitution of the coordinated organic ligand may occur despite the complex fragility in a basic medium or in the presence of oxidizing agents.