819796-37-7

Basic information

• Product Name: Cyclohexanecarboxylic acid, 6-hydroxy-3,3-dimethyl-2-oxo-, ethyl ester (9CI)
• Synonyms: Cyclohexanecarboxylic acid, 6-hydroxy-3,3-dimethyl-2-oxo-, ethyl ester (9CI)
• CAS NO: 819796-37-7
• Molecular Formula: C11H18O4
• Molecular Weight: 214.25822
• Product Categories: METHYL
• Mol File: 819796-37-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanecarboxylic acid, 6-hydroxy-3,3-dimethyl-2-oxo-, ethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxylic acid, 6-hydroxy-3,3-dimethyl-2-oxo-, ethyl ester (9CI)(819796-37-7)
• EPA Substance Registry System: Cyclohexanecarboxylic acid, 6-hydroxy-3,3-dimethyl-2-oxo-, ethyl ester (9CI)(819796-37-7)

Safety Data

• Hazardous Substances Data: 819796-37-7(Hazardous Substances Data)

Upstream product

• 870-63-3 prenyl bromide 
• 201230-82-2 carbon monoxide 
• 66248-79-1 ethyl 4,4-dimethyl-3-oxo-hex-5-enoate 

Relevant articles and documents

Sequential hydroformylation/aldol reactions: Versatile and controllable access to functionalised carbocycles from unsaturated carbonyl compounds

Three different modes of hydroformylation/aldol reaction sequences involving either acid-catalysed aldol reactions, Mukaiyama aldol addition of pre-formed enolsilanes or aldol addition of in situ generated boron enolates can be applied to unsaturated ketones and ketoesters to afford the corresponding carbocyclic aldol adducts in good yields proceeding through the intermediate activated ketoaldehydes. In selected cases, complimentary, synthetically useful diastereoselectivities were observed in the products.