82942-50-5

Basic information

• Product Name: 2,3-Dicyclohexylidenbutandisaeure-dimethylester
• CAS NO: 82942-50-5
• Molecular Weight: 306.402
• Mol File: 82942-50-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-Dicyclohexylidenbutandisaeure-dimethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-Dicyclohexylidenbutandisaeure-dimethylester(82942-50-5)
• EPA Substance Registry System: 2,3-Dicyclohexylidenbutandisaeure-dimethylester(82942-50-5)

Safety Data

• Hazardous Substances Data: 82942-50-5(Hazardous Substances Data)

Upstream product

• 762-42-5 dimethyl acetylenedicarboxylate 
• 930-82-5 3,3-pentamethylenediazirine 
• 82942-51-6 1,2-Diazaspiro<4.5>deca-1,3-dien-3,4-dicarbonsaeure-dimethylester 
• 82942-47-0 dimethyl spiro<2.5>oct-1-ene-1,2-dicarboxylate 

Relevant articles and documents

Synthesis of Spiro Compounds via Photoisomerisation of Spirodiazirines in the Presence of Alkynes

Selective irradiation of 1,2-diazaspirooct-1-ene (1) in the presence of dimethyl acetylenedicarboxylate (3) yields the spiro-3H-pyrazole 4 via photoisomerisation of 1 to intermediate diazocyclohexane (2) followed by 1,3-dipolar cycloaddition to 3.The strong dipolarophile dimethyl spirooct-1-ene-1,2-dicarboxylate (6), formed by photoelimination of nitrogen from 4, and its reaction products with 2 are obtained as further products.