832-64-4 Usage
Description
4-Methylphenanthrene is a derivative of phenanthrene, which is a polycyclic aromatic hydrocarbon (PAH) and an environmental pollutant. It is characterized by the presence of a methyl group attached to the fourth carbon atom of the phenanthrene molecule, giving it unique chemical properties and potential applications in various industries.
Uses
Used in Chemical Synthesis:
4-Methylphenanthrene is used as a chemical intermediate for the synthesis of various organic compounds, including pharmaceuticals, agrochemicals, and dyes. Its unique structure allows for selective functionalization and modification, making it a valuable building block in organic chemistry.
Used in Environmental Research:
As a derivative of phenanthrene, 4-methylphenanthrene is used in environmental research to study the behavior, fate, and transport of PAHs in the environment. Understanding the properties and effects of these compounds is crucial for assessing their impact on ecosystems and human health.
Used in Analytical Chemistry:
4-Methylphenanthrene is employed as a reference compound in analytical chemistry for the development and validation of analytical methods, such as chromatography and mass spectrometry. Its distinct chemical properties make it suitable for evaluating the performance of these techniques in detecting and quantifying PAHs and their derivatives.
Used in Material Science:
4-Methylphenanthrene has potential applications in material science, particularly in the development of advanced materials with unique optical, electronic, and thermal properties. Its molecular structure can be utilized to design and synthesize novel materials with specific characteristics for various applications, such as sensors, energy storage, and optoelectronics.
Check Digit Verification of cas no
The CAS Registry Mumber 832-64-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 8,3 and 2 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 832-64:
(5*8)+(4*3)+(3*2)+(2*6)+(1*4)=74
74 % 10 = 4
So 832-64-4 is a valid CAS Registry Number.
InChI:InChI=1/C15H12/c1-11-5-4-7-13-10-9-12-6-2-3-8-14(12)15(11)13/h2-10H,1H3
832-64-4Relevant articles and documents
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Whitlock,H.W. et al.
, p. 485 - 491 (1971)
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Construction of Phenanthrenes and Chrysenes from β-Bromovinylarenes via Aryne Diels-Alder Reaction/Aromatization
Singh, Vikram,Verma, Ram Subhawan,Khatana, Anil K.,Tiwari, Bhoopendra
, p. 14161 - 14167 (2019/10/28)
A highly efficient transition-metal-free general method for the synthesis of polycyclic aromatic hydrocarbons like phenanthrenes and chrysenes (and tetraphene) from β-bromovinylarenes and arynes has been developed. The reactions proceed via an aryne Diels-Alder (ADA) reaction, followed by a facile aromatization. This is the first report on direct construction of chrysenes (and tetraphene) using the ADA approach. Unlike the literature method which is limited to only 9/10-substituted derivatives, this method gives access to a wide variety of functionalized phenanthrenes.
Further insight into the photochemical behavior of 3-aryl-N-(arylsulfonyl)propiolamides: tunable synthetic route to phenanthrenes
Chen, Ming,Zhao, Xinxin,Yang, Chao,Wang, Yanpei,Xia, Wujiong
, p. 12022 - 12026 (2017/03/01)
Reported herein is further insight into the photochemical behaviour of 3-aryl-N-(arylsulfonyl)-propiolamides, which provides a straightforward way to access meaningful phenanthrenes. Mechanistic investigation indicated that aryl migration, C-C coupling, 1,3-hydrogen shift, desulfonylation and elimination were involved in the process. Moreover, this protocol allowed for scale-up using a flow reactor.
