835-06-3

Basic information

• Product Name: 3-METHOXYPHENANTHRENE
• Synonyms: 3-METHOXYPHENANTHRENE
• CAS NO: 835-06-3
• Molecular Formula: C₁₅H₁₂O
• Molecular Weight: 208.26
• Mol File: 835-06-3.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-METHOXYPHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHOXYPHENANTHRENE(835-06-3)
• EPA Substance Registry System: 3-METHOXYPHENANTHRENE(835-06-3)

Safety Data

• Hazardous Substances Data: 835-06-3(Hazardous Substances Data)

Upstream product

• 27570-08-7 4-(2-bromo-vinyl)-anisole 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 6630-33-7 ortho-bromobenzaldehyde 
• 130089-19-9 1-bromo-2-(2-methoxyethenyl)benzene 
• 10365-98-7 3-methoxyphenylboronic acid 
• 1024598-29-5 3'-methoxy-2-(2''-methoxyvinyl)-1,1'-biphenyl 
• 75-89-8 2,2,2-trifluoroethanol 
• 1694-19-5 E-1-(phenyl)-2-(4'-methoxyphenyl)ethene 
• 67-56-1 methanol 

Downstream Products

• 100780-04-9 (-)-(R)-3,3'-dihydroxy-4,4'-biphenanthrene 
• 7470-21-5 1-(3-methoxy-9-phenanthrenyl)ethanone 

Relevant articles and documents

Construction of Phenanthrenes and Chrysenes from β-Bromovinylarenes via Aryne Diels-Alder Reaction/Aromatization

A highly efficient transition-metal-free general method for the synthesis of polycyclic aromatic hydrocarbons like phenanthrenes and chrysenes (and tetraphene) from β-bromovinylarenes and arynes has been developed. The reactions proceed via an aryne Diels-Alder (ADA) reaction, followed by a facile aromatization. This is the first report on direct construction of chrysenes (and tetraphene) using the ADA approach. Unlike the literature method which is limited to only 9/10-substituted derivatives, this method gives access to a wide variety of functionalized phenanthrenes.

A combined experimental and computational study on the cycloisomerization of 2-ethynylbiaryls catalyzed by dicationic arene ruthenium complexes

Ruthenium-catalyzed cycloisomerization of 2-ethynylbiaryls was investigated to identify an optimal ruthenium catalyst system. A combination of [η6-(p-cymene)RuCl2(PR3)] and two equivalents of AgPF6 effectively converted 2-ethynylbiphenyls into phenanthrenes in chlorobenzene at 120 °C over 20 h. Moreover, 2-ethynylheterobiaryls were found to be favorable substrates for this ruthenium catalysis, thus achieving the cycloisomerization of previously unused heterocyclic substrates. Moreover, several control experiments and DFT calculations of model complexes were performed to propose a plausible reaction mechanism.

Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles

A continuing goal in catalysis is to unite the advantages of homogeneous and heterogeneous catalytic processes. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this unification can also be supplemented by the ability