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847753-50-8

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847753-50-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 847753-50-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,4,7,7,5 and 3 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 847753-50:
(8*8)+(7*4)+(6*7)+(5*7)+(4*5)+(3*3)+(2*5)+(1*0)=208
208 % 10 = 8
So 847753-50-8 is a valid CAS Registry Number.

847753-50-8Relevant articles and documents

Bimetallic zirconium amine bis(phenolate) polymerization catalysts: Enhanced activity and tacticity control for polyolefin synthesis

Radlauer, Madalyn R.,Agapie, Theodor

supporting information, p. 3247 - 3250 (2014/08/05)

Binucleating multidentate amine bis(phenolate) ligands with rigid terphenyl backbones were designed to support two zirconium centers locked in close proximity. Polymerizations of propylene or 1-hexene with the synthesized bimetallic precatalysts resulted in polymers with significantly higher isotacticity (up to 79% mmmm) in comparison to the stereoirregular polymers produced with previously reported Cs-symmetric monometallic analogues. The bimetallic precatalysts also display higher activity (up to 124 kg of poly(1-hexene) (mmol of Zr)-1 h-1), in comparison to the monometallic analogues, and among the highest activities reported for nonmetallocene catalysts. The stereocontrol is consistent with a bimetallic mechanism involving remote steric interactions with the ligand sphere of the second metal center.

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