84835-92-7

Basic information

• Product Name: N(C₂H₅)4⁽¹⁺⁾*Pt(P(C₆H₅)3)Cl₃^(1-)=N(C₂H₅)4PtP(C₆H₅)3Cl₃
• CAS NO: 84835-92-7
• Molecular Weight: 693.983
• Mol File: 84835-92-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N(C₂H₅)4⁽¹⁺⁾*Pt(P(C₆H₅)3)Cl₃^(1-)=N(C₂H₅)4PtP(C₆H₅)3Cl₃(CAS DataBase Reference)
• NIST Chemistry Reference: N(C₂H₅)4⁽¹⁺⁾*Pt(P(C₆H₅)3)Cl₃^(1-)=N(C₂H₅)4PtP(C₆H₅)3Cl₃(84835-92-7)
• EPA Substance Registry System: N(C₂H₅)4⁽¹⁺⁾*Pt(P(C₆H₅)3)Cl₃^(1-)=N(C₂H₅)4PtP(C₆H₅)3Cl₃(84835-92-7)

Safety Data

• Hazardous Substances Data: 84835-92-7(Hazardous Substances Data)

Upstream product

• 16887-00-6 chloride 
• 60243-31-4 trans-Pt(PPh₃)(pyridine)Cl₂ 
• 60243-32-5 Pt(P(C₆H₅)3)Cl₂CH₃NC₅H₄ 
• 133170-89-5 Pt(P(C₆H₅)3)Cl₂NH₂C₄H₉ 

Downstream Products

• 263155-77-7 trans-Pt(PPh₃)BrCl₂^(1-) 
• 60243-32-5 Pt(P(C₆H₅)3)Cl₂CH₃NC₅H₄ 
• 133170-89-5 Pt(P(C₆H₅)3)Cl₂NH₂C₄H₉ 
• 60243-31-4 trans-Pt(PPh₃)(pyridine)Cl₂ 
• 117319-22-9 trans-Pt(PPh₃)(MeOH)Cl₂ 
• 75247-42-6 trans-[Pt(PPh₃)(diethyl sulphide)Cl₂] 

Relevant articles and documents

Kinetics of the reversible displacement of chloride by amines under the trans effect of phosphines, phosphites, and arsines

The rate and equilibrium constants are reported for the reaction [Pt(L)Cl3] + am → trans-[Pt(L)(am)Cl2] + Cl (L = PMe3, PEt3, P-n-Bu3, PPh3, P(OMe)3, AsEt3; am is one of a series of amines and heterocyclic bases covering a wide range of basicity) in methanol at 30.0°C, μ = 0.50. The behavior patterns are discussed and compared with those of complexes where L is a sulfur donor ligand. The lability is strongly dependent upon the nature of the donor atom (P, As, or S) but far less sensitive to the nature of the substituents.