851363-60-5Relevant articles and documents
Higherature monoclinic α-SrHfF6, and isostructural α-SrZrF6: Associating Hf2F12 bipolyhedra and SrF8 snub disphenoids.
Laval, Jean-Paul,Mayet, Richard
, p. 229 - 235 (2018/02/14)
The structure of the higherature monoclinic variety α-SrHfF6 (strontium hafnium hexafluoride) [and of isostructural α-SrZrF6 (strontium zirconium hexafluoride)] associates Hf2F12 bipolyhedra and SrF8 snub disphenoids, forming zigzag twisted [SrF6]n layers. The distribution of the Hf and Sr polyhedra forms a three-dimensional framework which can be related to the family of anion-excess ReO3-related superstructures. α-SrHfF6 corresponds to a new ABX6 type and is compared to the other main families already described. A partial amorphization of this structure is observed in samples quenched from the melt.The crystal structure of α-SrHfF6 corresponds to a new structure type in the ABX6 series. It associates Hf2F12 bipolyhedra and SrF8 snub disphenoids, forming zigzag twisted [SrF6]n layers.
Thermal stability and X-ray-luminescent properties of fluorozirconates and fluorosulfatozirconates
Godneva,Boroznovskaya,Motov,Klimkin,Mikhailova
, p. 563 - 567 (2009/06/19)
The thermolysis of fluorozirconates (M2ZrF6, M 5Zr4F21 ? 3H2O, MZrF 5 ? H2O, Rb2Zr3OF12, and Cs2Zr3F14/sub
Formation and calculations of the simple terminal triplet pnictinidene molecules n÷MF3, P÷MF3, and As÷MF3 (M = Ti, Zr, Hf)
Wang, Xuefeng,Lyon, Jonathan T.,Andrews, Lester
, p. 6297 - 6302 (2009/12/04)
Laser-ablated Ti, Zr, and Hf atoms react with NF3, PF 3, or AsF3 to produce triplet state terminal pnictinidene N÷MF3, P÷MF3, or As÷MF3 molecules, which are trapped in an argon matrix. Prod