85335-84-8

Basic information

• Product Name: (2-Bromo-3-chloro-1-chloromethyl-propylsulfanyl)-benzene
• Synonyms: (2-Bromo-3-chloro-1-chloromethyl-propylsulfanyl)-benzene
• CAS NO: 85335-84-8
• Molecular Weight: 314.073
• Mol File: 85335-84-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2-Bromo-3-chloro-1-chloromethyl-propylsulfanyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Bromo-3-chloro-1-chloromethyl-propylsulfanyl)-benzene(85335-84-8)
• EPA Substance Registry System: (2-Bromo-3-chloro-1-chloromethyl-propylsulfanyl)-benzene(85335-84-8)

Safety Data

• Hazardous Substances Data: 85335-84-8(Hazardous Substances Data)

Upstream product

• 110-57-6 trans-1,4-dichlorobut-2-ene 
• 882-33-7 diphenyldisulfane 
• 28074-23-9 phenylsulfenyl bromide 

Downstream Products

• 85335-87-1 <3-(phenylthio)-1,3-butadienyl>triphenylphosphonium chloride 
• 85335-90-6 2-((2Z,4Z)-5-Phenyl-2-phenylsulfanyl-penta-2,4-dienyl)-hexanedioic acid dimethyl ester 
• 85336-08-9 2-Oxo-1-((2Z,4Z)-5-phenyl-2-phenylsulfanyl-penta-2,4-dienyl)-cyclopentanecarboxylic acid methyl ester 
• 85335-88-2 dimethyl 2-(2-(phenylthio)-2-butenyl)adipate 
• 85336-04-5 2-(phenylthio)-10a-acetyl-9,10-dihydro-1H-phenanthrene 
• 85336-05-6 spiro<2-methyl-5-(phenylthio)-2,4-cyclohexadiene-1,2'-tetralone> 
• 85335-94-0 4-(phenylthio)-6-carbomethoxybicyclo<4.4.0>deca-1,3-diene 
• 85335-96-2 4-(phenylthio)-6-carbomethoxybicyclo<4.3.0>nona-1,3-diene 
• 85335-92-8 C₁₈H₁₈OS 
• 85335-98-4 4-(phenylthio)-6-methylbicyclo<4.4.0>deca-1,3-dien-7-one 
• 85336-07-8 (E)-1-chloro-3-(phenylthio)-1,3-butadiene 
• 97644-86-5 2-carbomethoxy-2-(4-chloro-3-(phenylthio)-(E)-2-butenyl)-1-cyclopentanone 
• 85335-92-8 1-phenyl-4-(phenylthio)-5-methoxy-1,3-pentadiene 
• 97644-90-1 1-phenyl-4-(phenylthio)-5-methoxy-1,3-pentadiene 

Relevant articles and documents

The Robinson Transposition Reaction. Conjugate-Addition/Intramolecular Wittig Reactions of Enolates with triphenylphosphonium Chloride

The phosphonium salt described reacts with certain enolates to produce dienyl sulfides that may be subsequently hydrolyzed to afford enones that are regiotransposed relative to the standard Robinson annulation product.