856633-77-7

Basic information

• Product Name: 2-[3-(2-nitro-phenyl)-3-oxo-propyl]-1,1-dioxo-1λ⁶-benz[d]isothiazol-3-one
• Synonyms: 2-[3-(2-nitro-phenyl)-3-oxo-propyl]-1,1-dioxo-1λ⁶-benz[d]isothiazol-3-one
• CAS NO: 856633-77-7
• Molecular Weight: 360.347
• Mol File: 856633-77-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[3-(2-nitro-phenyl)-3-oxo-propyl]-1,1-dioxo-1λ⁶-benz[d]isothiazol-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[3-(2-nitro-phenyl)-3-oxo-propyl]-1,1-dioxo-1λ⁶-benz[d]isothiazol-3-one(856633-77-7)
• EPA Substance Registry System: 2-[3-(2-nitro-phenyl)-3-oxo-propyl]-1,1-dioxo-1λ⁶-benz[d]isothiazol-3-one(856633-77-7)

Safety Data

• Hazardous Substances Data: 856633-77-7(Hazardous Substances Data)

Upstream product

• 176859-85-1 3-(dimethylamino)-1-(2-nitrophenyl)propan-1-one 
• 81-07-2 saccharin 
• 577-59-3 2-acetylnitrobenzene 
• 67-68-5 dimethyl sulfoxide 

Downstream Products

• 363-36-0 kynuramine 
• 131620-12-7 2-[3-(2-amino-phenyl)-3-oxo-propyl]-1,1-dioxo-1λ⁶-benz[d]isothiazol-3-one 

Relevant articles and documents

Oxidative C-S bond cleavage reaction of DMSO for C-N and C-C bond formation: New Mannich-type reaction for β-amino ketones

A novel oxidative C-S bond cleavage reaction of DMSO for N-methylation and subsequent C-C bond formation is described. A series of aryl ketones as well as acetone derivatives could be selectively converted into the corresponding β-amino ketones. Mechanistic studies suggested that N-methylation between imine and DMSO was involved in the reaction.