858520-08-8

Basic information

• Product Name: μ-oxobis[(2,4-dimethylbenzenesulfonato)tri-p-tolylbismuth]
• CAS NO: 858520-08-8
• Molecular Weight: 1351.2
• Mol File: 858520-08-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: μ-oxobis[(2,4-dimethylbenzenesulfonato)tri-p-tolylbismuth](CAS DataBase Reference)
• NIST Chemistry Reference: μ-oxobis[(2,4-dimethylbenzenesulfonato)tri-p-tolylbismuth](858520-08-8)
• EPA Substance Registry System: μ-oxobis[(2,4-dimethylbenzenesulfonato)tri-p-tolylbismuth](858520-08-8)

Safety Data

• Hazardous Substances Data: 858520-08-8(Hazardous Substances Data)

Upstream product

• 858520-14-6 p-Tol₃Bi(OSO₂C₆H₃Me₂-2,4)2 
• 7732-18-5 water 

Downstream Products

• 6729-64-2 tri(p-tolyl)bismuth dichloride 
• 5142-75-6 tri(p-tolyl)bismuth 
• 107536-32-3 tris(4-methylphenyl)bismuth diacetate 

Relevant articles and documents

Synthesis, structure and reactions of μ- oxobis(arenesulfonatotriarylbismuth)

Hydrolysis of triarylbismuth bis(arenesulfonates) in acetone gives bismuth derivatives of the general formula [Ar3Bi(OSO2Ar')] 2O (Ar = Ph, p-Tol; Ar' = Ph, C6H4Me-4, C 6H3Me2-2,4, C6H3Me 2-3,4). The structure of μ-oxobis[(3,4-dimethylbenzenesulfonato) triphenylbismuth] was established by means of X-ray diffraction. The molecule has a linear centrosymmetric structure with the bridging oxygen atom in the inversion center. The bismuth atom has a distorted trigonal bipyramidal coordination with the bridging oxygen atom and the arenesulfonate group in axial positions. The Bi-C and Bi-Oterm distances are 2.200(2), 2.204(3), and 2.442(2) A, and the Bi-Obr distances are 2.067(1) A. 2004 MAIK "Nauka/Interperiodica".