864550-95-8

Basic information

• Product Name: 2-bromo-9-hexylcarbazole
• CAS NO: 864550-95-8
• Molecular Weight: 330.267
• Mol File: 864550-95-8.mol
• Article Data: 3

Chemical Properties

• Melting Point: 40.0 to 44.0 °C
• CAS DataBase Reference: 2-bromo-9-hexylcarbazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-9-hexylcarbazole(864550-95-8)
• EPA Substance Registry System: 2-bromo-9-hexylcarbazole(864550-95-8)

Safety Data

• Hazardous Substances Data: 864550-95-8(Hazardous Substances Data)

Usage

General Description

2-bromo-9-hexylcarbazole is a chemical compound consisting of a carbazole ring with a hexyl group and a bromine atom attached to it. It is a heterocyclic compound that has potential applications in the field of organic electronics and material science due to its semiconducting properties. The hexyl group attached to the carbazole ring contributes to its solubility in organic solvents, making it suitable for use in various organic electronic devices such as organic light-emitting diodes (OLEDs) and organic photovoltaic cells. The bromine atom on the carbazole ring can also potentially modify the chemical and physical properties of the compound, making it useful for further chemical synthesis and functionalization. Overall, 2-bromo-9-hexylcarbazole is a versatile chemical with potential applications in the development of advanced electronic materials.

Upstream product

• 98-80-6 phenylboronic acid 
• 70873-41-5 4-bromo-2-nitro-1-phenylbenzene 
• 3460-18-2 1,4-dibromo-2-nitrobenzene 
• 3652-90-2 2-bromo-9H-carbazole 
• 111-25-1 1-bromo-hexane 

Downstream Products

• 1339953-35-3 9-hexylcarbazol-6-[4',4',5',5'-tetramethyl(1',3',2')dioxaborolan-2-yl] 
• 1340541-09-4 bis(3,3'-{5',15'-diphenylporphyrinato(zinc(II))-10',20'-yl})-9-hexyl-carbazole 
• 1340541-07-2 3-(5,10,15-tris(4-methylphenyl)porphyrinato(palladium)(II)-20-yl)-9-hexyl-carbazole 
• 1340541-06-1 3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole 
• 1340541-05-0 3-(5',10',15'-triphenylporphyrinato(zinc)(II)-20'-yl)-9-hexyl-carbazole 

Relevant articles and documents

Iridium complexes based on carbazole-oxadiazole serving as main ligands as well as preparation and application method thereof

The invention relates to iridium complexes based on carbazole-oxadiazole serving as main ligands. The series of iridium complexes take two carbazole-oxadiazole derivatives as the main ligands and picolinic acid as an auxiliary ligand. The iridium complexes with the structure have the advantages of high light-emitting efficiency, simple process, low manufacturing cost and the like. The iridium complexes can be used for adjusting the light-emitting organic electroluminescence range and the light-emitting efficiency by changing the number of F atoms on the oxadiazole and the connection position of the position. Moreover, through the application of the iridium complexes synthesized by the method, the life is relatively short and the properties of devices are improved.

Practical syntheses of N-hexylcarbazol-2-yl- and -3-yl-boronic acids, their cross-coupled products and a derived tris-cyclometalated (pyridin-2-yl) carbazole iridium(III) complex

The syntheses of N-hexylcarbazol-2-yl- and -3-yl-boronic acids (1 and 2) are described on a ca. 7 g scale, starting from commercially available 2,5-dibromonitrobenzene (4) and carbazole (11), respectively. Compounds 1 and 2 underwent efficient palladium-catalyzed cross-coupling reactions under Suzuki-Miyaura conditions to yield products 17,18 and 20. Compound 18 reacted with IrCl3 to give the tris-cyclometalated (pyridin-2-yl)carbazole iridium(III) complex 21, the X-ray crystal structure of which is reported. Georg Thieme Verlag Stuttgart.