86718-78-7

Basic information

• Product Name: 1-(4-fluorophenyl)-3-buten-1-ol
• CAS NO: 86718-78-7
• Molecular Weight: 166.195
• Mol File: 86718-78-7.mol
• Article Data: 90

Chemical Properties

• CAS DataBase Reference: 1-(4-fluorophenyl)-3-buten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-fluorophenyl)-3-buten-1-ol(86718-78-7)
• EPA Substance Registry System: 1-(4-fluorophenyl)-3-buten-1-ol(86718-78-7)

Safety Data

• Hazardous Substances Data: 86718-78-7(Hazardous Substances Data)

Upstream product

• 24850-33-7 allyltributylstanane 
• 459-57-4 4-fluorobenzaldehyde 
• 1730-25-2 allylmagnesium bromide 
• 2622-05-1 allylmagnesium bromide 
• 613-94-5 benzoic acid hydrazide 
• 106-95-6 allyl bromide 
• 459-56-3 4-fluorobenzylic alcohol 
• 107-37-9 allyltrichlorosilane 
• 107-18-6 allyl alcohol 
• 591-87-7 Allyl acetate 
• 191732-48-6 (E)-(3-bromoprop-1-en-1-yl)tributylstannane 
• 762-72-1 allyl-trimethyl-silane 
• 556-56-9 allyl iodid 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 1210066-87-7 (E)-4-(4-fluorophenyl)-4-hydroxybut-2-enyl propionate 
• 1210066-89-9 (E)-4-(4-fluorophenyl)-4-hydroxybut-2-enyl pivalate 
• 1143515-07-4 1-[1-(benzyloxy)-but-3-enyl]-4-fluorobenzene 
• 1402042-55-0 4-(benzyloxy)-4-(4-fluorophenyl)-butan-1-ol 
• 1402042-56-1 4-(benzyloxy)-4-(4-fluorophenyl)-butanal 
• 1402042-57-2 1-[4-(benzyloxy)-4-(4-fluorophenyl)-butyl]-4-(2-methoxyphenyl)piperazine 
• 857-62-5 Anisopirol 
• 1480-19-9 fluanisone 
• 1158557-09-5 5-benzyl-3-(4-fluorophenyl)-2-Δ²-isoxazoline 
• 1160472-60-5 3-(4-fluorophenyl)-4,5-dihydroisoxazole-5-carbonitrile 
• 833462-37-6 3-(4-fluorophenyl)-5-[(phenylselanyl)methyl]-4,5-dihydroisoxazole 
• 1470003-84-9 2,6-bis(4-fluorophenyl)-tetrahydro-2H-pyran-4-ol 
• 1470003-90-7 9-(2,6-bis(4-fluorophenyl)tetrahydro-2H-pyran-4-yl)-9H-purin-6-amine 
• 1470003-87-2 2,6-bis(4-fluorophenyl)tetrahydro-2H-pyran-4-yl 4-methylbenzenesulfonate 

Relevant articles and documents

Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant

This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.

Visible Light-Promoted Recyclable Carbon Nitride-Catalyzed Dioxygenation of β,γ-Unsaturated Oximes

A visible-light-induced dioxygenation of β,γ-unsaturated oximes for the synthesis of diverse useful isoxazolines bearing a hydroxyl moiety was developed by employing graphitic carbon nitride (g-C3N4) as a heterogeneous photocatalyst under an air atmosphere. Noted that, the eminent advantages of this metal-free protocol include step economy, easy operation, a recyclable photocatalyst, external reductant-/oxidant-free and mild reaction conditions. Additionally, mechanistic studies indicated hydroxyl radical was generated under the photocatalysis of g-C3N4.

Copper-catalyzed radical oxyallylation of olefins for the construction of alkene-containing isoxazolines

A radical-mediated approach to alkene oxyallylation using allylic oximes is described. The reaction proceeds under copper-catalytic redox-neutral conditions and tolerates various functional groups. This protocol thus enables the synthesis of structurally valuable isoxazolines and the introduction of a versatile olefin motif in a single step.