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87750-49-0

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87750-49-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 87750-49-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,7,7,5 and 0 respectively; the second part has 2 digits, 4 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 87750-49:
(7*8)+(6*7)+(5*7)+(4*5)+(3*0)+(2*4)+(1*9)=170
170 % 10 = 0
So 87750-49-0 is a valid CAS Registry Number.

87750-49-0Downstream Products

87750-49-0Relevant articles and documents

Acylation du trifluoromethoxybenzene en catalyse HF-BF3

Desbois, Michel

, p. 885 - 890 (2007/10/02)

Friedel and Crafts acylation of trifluoromethoxy- and trifluoromethyl-thiobenzene fails to give ketones in a one step synthesis if chlorinated Lewis acids (AlCl3) are used, because of halogen exchange on the -OCF3 and -SCF3 groups.The use of a fluorinated catalyst system such as HF-BF3 avoids exchange reactions and acylation occurs smoothly under mild conditions: - Low temperature and pressure - High yields (very often >90 percent) - Very high para-regioselectivity.Related reactions such as formylation or sulfonylation can also be achieved under similar conditions.

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