88048-84-4

Basic information

• Product Name: Benzaldehyde, 2-(phenylseleno)-
• CAS NO: 88048-84-4
• Molecular Formula: C13H10OSe
• Molecular Weight: 261.182
• Mol File: 88048-84-4.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-(phenylseleno)-(88048-84-4)
• EPA Substance Registry System: Benzaldehyde, 2-(phenylseleno)-(88048-84-4)

Safety Data

• Hazardous Substances Data: 88048-84-4(Hazardous Substances Data)

Upstream product

• 26260-02-6 2-iodobenzaldehyde 
• 1666-13-3 diphenyl diselenide 
• 5440-69-7 N-isopropylbenzamide 
• 100-52-7 benzaldehyde 
• 6630-33-7 ortho-bromobenzaldehyde 
• 40138-16-7 2-formylbenzene boronic acid 
• 864512-14-1 2-iodophenyl 4-chlorobenzenesulfonate 
• 645-96-5 Benzeneselenol 
• 68-12-2 N,N-dimethyl-formamide 
• 591-51-5 phenyllithium 
• 128750-60-7 1-chloro-1-phenyl-3H-2,1-benzoxaselenole 
• 23974-72-3 sodium phenylselenide 
• 89-98-5 2-chloro-benzaldehyde 

Downstream Products

• 1421765-47-0 2-(phenylselenyl)phenyldi-2-pyrrolmethane 
• 1421768-87-7 C₂₁H₁₅BF₂N₂OSe 
• 1421768-85-5 C₂₁H₁₅BF₂N₂Se 
• 128750-62-9 1-chloro-3-mesityl-1-phenyl-3H-2,1-benzoxaselenole 
• 128750-61-8 1-chloro-1,3-diphenyl-3H-2,`1-benzoxaselenole 
• 128750-60-7 1-chloro-1-phenyl-3H-2,1-benzoxaselenole 
• 128750-70-9 1-hydroxy-1-phenyl-3H-2,1-benzoxaselenole 
• 25562-75-8 2-(phenylseleno)benzyl chloride 
• 52199-19-6 phenyl(2-(phenylselanyl)phenyl)methanone 
• 88048-86-6 bis<2-(diphenylmethyl)phenyl>diselenide 
• 82238-27-5 cis-9-(pentadeuteriophenyl)selenoxanthene-N-(benzenesulfonyl)selenilimine 
• 82238-27-5 trans-9-(pentadeuteriophenyl)selenoxanthene-N-(benzenesulfonyl)selenilimine 
• 82238-23-1 cis-9-Phenylselenoxanthene-N-(p-toluenesulfonyl)-selenilimine 
• 82238-23-1 trans-9-Phenylselenoxanthene-N-(p-toluenesulfonyl)selenilimine 

Relevant articles and documents

A new synthesis of highly active Rh-Co alloy nanoparticles supported on N-doped porous carbon for catalytic C-Se cross-coupling and p -nitrophenol hydrogenation reactions

Bimetallic Rh-Co nanoparticles supported on nitrogen-doped porous carbon (Rh-Co/NPC) were synthesized from metal precursors and urea through a simple thermal decomposition/reduction under a nitrogen flow. The Rh-Co/NPC nanocatalyst which contains highly dispersed alloy nanoparticles (～6 nm) showed high catalytic performance as well as good recyclability for the C-Se coupling reaction of diphenyl diselenide and aryl boronic acid and p-nitrophenol reduction.

Ruthenium-Catalyzed C–H Selenylations of Benzamides

A convenient and effective protocol for the ruthenium-catalyzed C–H selenylations of benzamide was achieved under mild reaction conditions. The robust ruthenium catalyst tolerated a wide range of functional groups and set the stage for the preparation for diversely decorated benzamides. The amide directing group could be transferred to carboxylic acid, aldehyde and tetrazoles. Preliminary mechanistic study indicated a base-assisted electrophilic-type substitution C–H activation event.

METHOD OF PREPARING CORE-SHELL COPPER NANOPARTICLES IMMOBILIZED ON ACTIVATED CARBON AND METHOD OF PREPARING CHALCOGENIDE COMPOUND USING NANOPARTICLES AS CATALYST

Disclosed herein is a method of preparing a Cu/Cu2O core-shell copper nanoparticle catalyst having high catalytic activity from [Cu3(BTC)2] and NaBH4 via a simple chemical reduction method. Also disclosed is a method of preparing a chalcogenide compound by using the nanoparticle catalyst as a heterogeneous catalyst in a cross-coupling reaction between a chalcogenide precursor compound and a boron-containing compound. The disclosed cross-coupling reaction is performed via a simple process, and the disclosed nanoparticle catalyst is compatible with various substrates under mild reaction conditions and exhibits excellent recyclability without a reduction in catalytic activity.