88489-56-9

Basic information

• Product Name: 1-methoxy-2-(methoxy-d₃)benzene
• Synonyms: 1-methoxy-2-(methoxy-d₃)benzene
• CAS NO: 88489-56-9
• Molecular Weight: 141.142
• Mol File: 88489-56-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-methoxy-2-(methoxy-d₃)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-2-(methoxy-d₃)benzene(88489-56-9)
• EPA Substance Registry System: 1-methoxy-2-(methoxy-d₃)benzene(88489-56-9)

Safety Data

• Hazardous Substances Data: 88489-56-9(Hazardous Substances Data)

Upstream product

• 23726-00-3 <²H9>trimethylsulphoxonium iodide 
• 90-05-1 2-methoxy-phenol 
• 15199-43-6 d6-dimethyl sulfate 

Relevant articles and documents

Trideuteromethylation Enabled by a Sulfoxonium Metathesis Reaction

A conceptually novel sulfoxonium metathesis reaction between TMSOI and cost-effective DMSO-d6 is developed for the efficient generation of a new trideuteromethylation reagent TDMSOI. The new reagent TDMSOI is produced highly efficiently by simply heating a mixture of TMSOI and DMSO-d6 and directly used for subsequent trideuteromethylation in a "one-pot" operation. The preparative power of the new versatile reagent and the "one-pot" protocol is demonstrated by its use to install the ?CD3 moiety into broad functionalities including phenols, thiophenols, acidic amines, and enolizable methylene units in high yield and at a useful level of deuteration (>87% D).

A RAMAN SPECTROSCOPIC STUDY OF THE LOW-FREQUENCY VIBRATIONS OF o-DIMETHOXYBENZENE AND ITS METHYL DEUTERATED ANALOGUES

The low-frequency (100-400 cm-1) Raman spectra of liquid (at 300 K) and solid (at 130 K) veratrole (o-dimethoxybenzene), and its methyl deuterated analogues, have been measured.The methyl and methoxyl torsional transitions have been identified, and the corresponding rotational barriers have been determined.The interpretation of the spectra points to a conformationally mixed situation for solid veratrole, in which both planar and non-planar conformers may co-exist.