88533-61-3

Basic information

• Product Name: Phosphine oxide, (cyclohexylmethyl)diphenyl-
• CAS NO: 88533-61-3
• Molecular Formula: C19H23OP
• Molecular Weight: 298.365
• Mol File: 88533-61-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Phosphine oxide, (cyclohexylmethyl)diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine oxide, (cyclohexylmethyl)diphenyl-(88533-61-3)
• EPA Substance Registry System: Phosphine oxide, (cyclohexylmethyl)diphenyl-(88533-61-3)

Safety Data

• Hazardous Substances Data: 88533-61-3(Hazardous Substances Data)

Upstream product

• 69490-70-6 Triphenyl-hexahydrobenzyl-phosphonium 
• 5292-21-7 Cyclohexylacetic acid 
• 4559-70-0 Diphenylphosphine oxide 
• 136492-35-8 (diphenylphosphinomethyl)cyclohexane 
• 98-88-4 benzoyl chloride 
• 829-85-6 diphenylphosphane 
• 36838-04-7 α-Oxo-phenylmethan-diphenylphosphin 
• 1192-37-6 methylenecyclohexane 
• 2550-36-9 Cyclohexylmethyl bromide 
• 603-35-0 triphenylphosphine 
• 101674-30-0 cyclohexyltriphenylphosphonium bromide 

Downstream Products

• 190668-22-5 1-cyclohexyl-1-diphenylphosphinoylpropan-2-ol 
• 145653-05-0 (E)-4-cyclohexyl-4-diphenylphosphinoylbut-2-en-1-ol 
• 145652-98-8 4-cyclohexyl-4-diphenylphosphinoylbut-1-en-3-yl acetate 
• 145653-02-7 (E)-4-cyclohexyl-4-diphenylphosphynoylbut-2-en-1-yl acetate 
• 172513-30-3 1-Cyclohexyl-1-(diphenyl-phosphinoyl)-pentan-2-one 
• 122183-48-6 (1S,2R)-2-Cyclohexyl-2-(diphenyl-phosphinoyl)-1-phenyl-ethanol 

Relevant articles and documents

Palladium-catalyzed C(sp3)–P(III) bond formation reaction with acylphosphines as phosphorus source

Palladium-catalyzed C(sp3)–P(III) bond formation reaction for alkyl substituted phosphines preparation was developed. In this reaction, various alkyl bromides and limited alkyl chlorides reacted with acylphosphine under relative mild and easily accessible condition, and differential phosphines were afforded in good yields. This reaction made up the application of palladium catalysis in C(sp3)–P(III) bond formation, and indicated a practical application of acylphosphine as a phosphination reagent.

Copper-catalyzed allylic C-H phosphonation

An efficient copper-catalyzed allylic C-H phosphonation reaction has been developed under mild reaction conditions. This method exhibits high regioselectivity and stereoselectivity. Various alkenes with useful functional groups are compatible in this tran

CIS-OLEFINS FROM THE HORNER-WITTIG REACTION; ORIGIN AND OPTIMISATION OF STEREOCHEMISTRY

Conditions are described to produce high yields of erythro Horner-Wittig intermediates: stereospecific elimination gives cis-alkenes.