89333-85-7

Basic information

• Product Name: Silane, [1-(4-chlorophenyl)-2-propenyl]trimethyl-
• CAS NO: 89333-85-7
• Molecular Formula: C12H17ClSi
• Molecular Weight: 224.805
• Mol File: 89333-85-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [1-(4-chlorophenyl)-2-propenyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [1-(4-chlorophenyl)-2-propenyl]trimethyl-(89333-85-7)
• EPA Substance Registry System: Silane, [1-(4-chlorophenyl)-2-propenyl]trimethyl-(89333-85-7)

Safety Data

• Hazardous Substances Data: 89333-85-7(Hazardous Substances Data)

Upstream product

• 344437-67-8 (2-Benzenesulfonyl-2-methanesulfinyl-ethyl)-trimethyl-silane 
• 89333-90-4 (2-Benzenesulfonyl-2-methylsulfanyl-ethyl)-trimethyl-silane 
• 64489-06-1 trans-1-(benzylsulfonyl)-2-(trimethylsilyl)ethylene 
• 14774-78-8 4-chlorophenyl lithium 

Relevant articles and documents

NEW METHOD FOR REGIOSELECTIVE SYNTHESIS OF α-SUBSTITUTED ALLYLSILANES AND ITS APPLICATION TO THE SYNTHESIS OF E- AND Z-TAGETONES

Sequential addition of lithium salt of carbanion and tributylstannylmethyl iodide (3) to vinyl sulfone 2 afforded β-tributylstannyl sulfones 5, which gave substituted allylsilanes 1 in a regioselective manner by the smooth destannylsulfonation.Allylsilane 8 prepared by Michael type addition of isopropenyllithium to 2 was converted into tagetones (10). Keywords --- allylsilane; β-trimethylsylilvinyl sulfone; destannylsulfonation; tributylstannylmethyl iodide; tagetone; Michael addition