89353-62-8Relevant articles and documents
A nine carbon homologating system for skip-conjugated polyenes
Mustafa, Hussein H.,Baird, Mark S.,Al Dulayymi, Juma'A R.,Tverezovskiy, Viacheslav V.
, p. 34 - 42 (2014/07/08)
Ozonolysis of Z,Z,Z-cylonona-1,4,7-triene leads to a 1,9-difunctionalised Z,Z-3,6-nonadiene which is readily converted into a range of polyunsaturated pheromones and fatty acids.
Facile and efficient syntheses of (3Z,6Z,9Z)-3,6,9-nonadecatriene and homologues: Pheromone and attractant components of lepidoptera
Wang, Shifa,Zhang, Aijun
, p. 6929 - 6932 (2008/09/17)
Facile and efficient chemical syntheses of (3Z,6Z,9Z)-3,6,9-nonadecatriene and homologues from commercially available α-linolenic acid [(9Z,12Z,15Z)-9,12,15-octadecatrienoic acid] are reported. These straight-chain homoconjugated trienes are common sex pheromone and attractant components for many lepidopterous insect pests. The metal-catalyzed cross-coupling reactions between (9Z,12Z,15Z)-9,12,15-octadecatrienyl triflate and the appropriate Grignard reagents proceed very rapidly under notable mild conditions using Li2CuCl4 as catalyst in diethyl ether, and the resulting (3Z,6Z,9Z)-3,6,9-trienes with retention of geometrical configuration were in >92% isolated yield.
Facile Synthesis of 1,4-Dienic Compounds from 4-Pentyn-1-ol: Synthesis of Pheromone Components of Boarmia Selenaria and B. Rhomboidaria
Chattopadhyay, A.,Mamdapur, B.
, p. 2225 - 2234 (2007/10/02)
The bifunctionality of 4-pentyn-1-ol has been suitably exploited to prepare 1,4-dienic unit.This has been applied for the synthesis of two important sex pheromone components.