918-84-3 Usage
Description
3-Chloro-3-methylpentane, also known as 3C3MP, is an organic compound with a molecular formula of C6H13Cl. It has a structure similar to tertiary chloride groups, which are formed as structural defects during the radical polymerization of vinyl chloride (VC). This makes 3C3MP an ideal model compound for studying the reactivity and applications of tertiary chloride defects in commercial PVC.
Uses
Used in Polymer Chemistry Research:
3C3MP is used as a model compound to study the reactivity of tertiary chloride defects present in commercial PVC. It helps researchers understand if these defects can act as active initiating species for metal-catalyzed living radical graft copolymerization, which is crucial for developing advanced polymer materials with improved properties.
Used in Organic Synthesis:
3C3MP can be used as a reactant to prepare chloro(1-ethyl-1-methylpropyl)magnesium, a Grignard reagent. This reagent is employed in the Kumada–Tamao–Corriu coupling reaction, a widely used cross-coupling reaction in organic synthesis. This reaction allows for the formation of carbon-carbon bonds between organic halides and organometallic compounds, enabling the synthesis of various complex organic molecules with potential applications in pharmaceuticals, materials science, and other fields.
Check Digit Verification of cas no
The CAS Registry Mumber 918-84-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,1 and 8 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 918-84:
(5*9)+(4*1)+(3*8)+(2*8)+(1*4)=93
93 % 10 = 3
So 918-84-3 is a valid CAS Registry Number.
InChI:InChI=1/C6H13Cl/c1-4-6(3,7)5-2/h4-5H2,1-3H3
918-84-3Relevant articles and documents
FeCl3-activated oxidation of alkanes by [Os(N)O 3]-
Yiu, Shek-Man,Wu, Zhi-Biao,Mak, Chi-Keung,Lau, Tai-Chu
, p. 14921 - 14929 (2007/10/03)
Although the ion [OsVIII(N)(O)3]- is a stable species and is not known to act as an oxidant for organic substrates, it is readily activated by FeCl3 in CH2Cl2/CH 3CO2H to oxidize alkanes efficiently at room temperature. The oxidation can be made catalytic by using 2,6-dichloropyridine N-oxide as the terminal oxidant. The active intermediates in stoichiometric and catalytic oxidation are proposed to be [(O)3OsVIII≡N-Fe III] and [Cl4(O)OsVIII≡N-Fe III], respectively.
