91968-37-5Relevant articles and documents
Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes
Dekhtyar’,Vostrikova,Zlotskii,Bogomazova,Mikhailova
, p. 650 - 655 (2019)
Abstract: The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mix
Reactions of trialkylalanes with cyclic acetals and orthoformates in CH2Cl2 and ClCH2CH2Cl as solvents
Gafarova,Dekhtyar',Dekhtyar',Fatykhov,Spirikhin,Vostrikova,Zlotskii,Dokichev
, p. 1003 - 1008 (2007/10/03)
Under mild conditions, trialkylalanes (Et3Al and Bu i3Al) in chlorine-containing solvents (CH 2Cl2 or ClCH2CH2Cl) react with cyclic acetals and orthoformates to form glycol monoethers and dialkylacetals, respectively, in high yields. The 1H NMR spectroscopic data demonstrate that CH2Cl2 or ClCH2CH 2Cl interacts with Bui3Al.
REDUCTION CLEAVAGE OF AROMATIC CYCLIC ACETALS WITH ZIRCONIUM CHLORIDE-LITHIUM ALUMINUM HYDRIDE
Shaozu, Wu,Tianhui, Ren,Ning, Chen,Yulan, Zhang
, p. 427 - 431 (2007/10/03)
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