92319-47-6

Basic information

• Product Name: heptyl cyclohexanecarboxylate
• Synonyms: heptyl cyclohexanecarboxylate;Cyclohexanecarboxylic acid heptyl ester
• CAS NO: 92319-47-6
• Molecular Formula: C₁₄H₂₆O₂
• Molecular Weight: 226.35504
• EINECS: 296-132-3
• Mol File: 92319-47-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 280.8°Cat760mmHg
• Flash Point: 113°C
• Appearance: /
• Density: 0.931g/cm³
• Vapor Pressure: 0.0037mmHg at 25°C
• Refractive Index: 1.458
• CAS DataBase Reference: heptyl cyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: heptyl cyclohexanecarboxylate(92319-47-6)
• EPA Substance Registry System: heptyl cyclohexanecarboxylate(92319-47-6)

Safety Data

• Hazardous Substances Data: 92319-47-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H26O2/c1-2-3-4-5-9-12-16-14(15)13-10-7-6-8-11-13/h13H,2-12H2,1H3

Upstream product

• 111-71-7 heptanal 
• 110-83-8 cyclohexene 
• 111-70-6 n-heptan1ol 
• 141-53-7 sodium formate 
• 629-04-9 1-Bromoheptane 
• 2043-61-0 cyclohexanecarbaldehyde 

Relevant articles and documents

Hydroesterification of alkenes with sodium formate and alcohols promoted by cooperative catalysis of Ru3(CO)12 and 2-pyridinemethanol

(Figure Presented) A chelation-assisted hydroesterification reaction of alkenes with sodium formate and alcohols that involves cooperative catalysis by Ru3(CO)12 and 2-pyridinemethanol is described. In this three-component coupling reaction, sodium formate serves as the carbon monoxide source.

Ruthenium Complex Catalyzed Intermolecular Hydroacylation and Transhydroformylation of Olefins with Aldehydes

Low-valent ruthenium complexes such as dodecacarbonyltriruthenium (Ru3(CO)12), (η4-1,5-cyclooctadiene)(η6-1,3,5-cyclooctatriene)ruthenium (Ru(COD)(COT)) and bis(η5-cyclooctadienyl)ruthenium showed high catalytic activity for the intermolecular hydroacylation of olefins with various aromatic and heteroaromatic aldehydes at 180-200 deg C for 24-48 h under an initial carbon monoxide pressure of 20 kg cm-2 to give unsymmetric ketones in moderate to good yields.In the reaction of 2-thiophenecarbaldehyde with cyclohexene, cyclohexyl 2-thienyl ketone was obtained in 62 percent yield.On the other hand, when the aliphatic aldehyde, heptanal, was treated with cyclohexene, the corresponding ketone was not obtained at all, and a transhydroformylation reaction proceeded; i.e., the formyl group of heptanal was apparently transformed to cyclohexene to give cyclohexanecarbaldehyde in 29 percent yield, together with their Tishchenko-type reaction products.