92345-90-9

Basic information

• Product Name: Benzaldehyde, 3,4-dimethoxy-2-(2-propenyl)-
• CAS NO: 92345-90-9
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 92345-90-9.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 3,4-dimethoxy-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 3,4-dimethoxy-2-(2-propenyl)-(92345-90-9)
• EPA Substance Registry System: Benzaldehyde, 3,4-dimethoxy-2-(2-propenyl)-(92345-90-9)

Safety Data

• Hazardous Substances Data: 92345-90-9(Hazardous Substances Data)

Upstream product

• 621-59-0 isovanillin 
• 106-95-6 allyl bromide 
• 74-88-4 methyl iodide 
• 18075-40-6 O-allylisovanillin 
• 18075-41-7 2-allyl-3-hydroxy-4-methoxybenzaldehyde 
• 74-83-9 methyl bromide 

Downstream Products

• 469898-63-3 3,4-dimethoxy-1-(1'-hydroxyethyl)-2-(prop-2'-enyl)benzene 
• 66967-26-8 3,4-dimethoxy-2-(2-propenyl)phenol 
• 408340-61-4 2-allyl-3,4-dimethoxybenzyl alcohol 
• 885316-25-6 2-allyl-1-(dimethoxymethyl)-3,4-dimethoxybenzene 
• 934749-60-7 2-cyano-3-(2-allyl-3,4-dimethoxyphenyl)-1-propen-3-ol 
• 1400026-40-5 2-(2-allyl-3,4-dimethoxy-phenyl)-1H-benzoimidazole 
• 1390647-73-0 3,4-dimethoxy-6-methyl-5,6-dihydro-benzo[4,5]imidazo[2,1-a]isoquinoline 
• 1394913-81-5 1-(2-allyl-3,4-dimethoxyphenyl)-3-(2-methoxyphenyl)propenone 
• 1394913-82-6 1-(2-allyl-3,4-dimethoxyphenyl)-3-(2-nitrophenyl)propenone 
• 1391762-23-4 3-(2-allyl-3,4-dimethoxyphenyl)-1,5-bis(furan-2-yl)pentane-1,5-dione 
• 1391762-24-5 3-(2-allyl-3,4-dimethoxyphenyl)-1,5-bis(thiophen-2-yl)pentane-1,5-dione 
• 1391762-17-6 3-(2-allyl-3,4-dimethoxyphenyl)-1,5-bis(2-methoxyphenyl)pentane-1,5-dione 
• 1391762-32-5 C₃₀H₃₁NO₄ 
• 1391762-19-8 3-(2-allyl-3,4-dimethoxyphenyl)-1,5-bis(3,4,5-trimethoxyphenyl)pentane-1,5-dione 

Relevant articles and documents

TBuO 2H/Cu(acac) 2-Mediated Intramolecular Oxidative Lactonization of o -Allyl Arylaldehydes: Synthesis of 1-Oxoisochromans

A concise route for the tBuO 2H/Cu(acac) 2-mediated synthesis of 1-oxoisochromans is described. This includes: (i) oxidation of oxygenated o -allyl arylaldehydes and (ii) sequential intramolecular lactonization of the resulting olefin-containing benzoic acids. A plausible mechanism is proposed and discussed.

Synthesis of Polysubstituted 3-Methylisoquinolines through the 6π-Electron Cyclization/Elimination of 1-Azatrienes derived from 1,1-Dimethylhydrazine

A convenient one pot microwave-assisted 6π-electron cyclization/aromatization approach toward 3-methylisoquinolines is reported. The starting 1-azatriene derivatives were prepared in situ by reaction of 2-propenylbenzaldehydes with 1,1-dimethylhydrazine, which exhibited superior performance when compared with other hydrazine derivatives. Minor amounts of the related 3,4-dihydro isoquinolines were formed concomitantly with the isoquinolines, and a mechanism for their generation was proposed. The reaction conditions were optimized, and its scope and limitations were explored. In general, the transformation proceeded in moderate to good yields.

Synthesis of 2-hydroxymethyl-2,3-dihydrobenzofurans

A one-pot protocol toward 2-hydroxymethyl-2,3-dihydrobenzofurans (1) starting with oxygenated o-allylbenzaldehydes (3) was described. The facile one-pot process was carried out by the oxidation of o-allylbenzaldehydes (3) with Oxone in the co-solvent of acetone and DMF in the presence of aqueous EDTA solution and then intramolecular ring-closure of the resulting o-allylphenols (2) in acceptable yields.