92356-36-0

Basic information

• Product Name: Ethanone, 1-(4-methylbicyclo[2.2.1]hept-5-en-2-yl)-, exo- (9CI)
• Synonyms: Ethanone, 1-(4-methylbicyclo[2.2.1]hept-5-en-2-yl)-, exo- (9CI)
• CAS NO: 92356-36-0
• Molecular Formula: C10H14O
• Molecular Weight: 150.21756
• Product Categories: ACETYLGROUP
• Mol File: 92356-36-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(4-methylbicyclo[2.2.1]hept-5-en-2-yl)-, exo- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4-methylbicyclo[2.2.1]hept-5-en-2-yl)-, exo- (9CI)(92356-36-0)
• EPA Substance Registry System: Ethanone, 1-(4-methylbicyclo[2.2.1]hept-5-en-2-yl)-, exo- (9CI)(92356-36-0)

Safety Data

• Hazardous Substances Data: 92356-36-0(Hazardous Substances Data)

Upstream product

• 3727-31-9 2-methyl-1,3-cyclopentadiene 
• 78-94-4 methyl vinyl ketone 
• 542-92-7 cyclopenta-1,3-diene 

Relevant articles and documents

Silica-supported chlorometallate(iii) ionic liquids as recyclable catalysts for Diels-Alder reaction under solventless conditions

A range of Lewis acidic metal chlorides were tested as homogeneous catalysts in a model Diels-Alder reaction; AlCl3and GaCl3performed best in terms of conversion andendo : exoselectivity. Based on this outcome, the corresponding chlorometallate(iii) ionic liquids were tested as homogeneous catalysts, without a decrease in performance compared to the chlorides. Finally, these ionic liquids were heterogenised by covalent tethering of the cation onto a multimodal porous silica support; such supported chlorogallate(iii) ionic liquids are reported for the first time. Supported chlorometallate(iii) ionic liquids were used as recyclable heterogeneous catalysts for the Diels-Alder reaction under solventless conditions. High yields (99%) and highendo-selectivities (95%) were obtained after very short reaction times (5 min) at near-ambient temperature (25 °C).

New Carbonyl Compounds in the High-Boiling Fraction of Lavender Oil

The occurrence of a series of new constituents which can be considered as Diels-Alder adducts of methyl vinyl ketone and ocimene (1-4), myrcene (9,10) or β-farnesene (11,12), respectively, was reported.Furthermore, the structures of four isomeric cyclohexene derivatives could be established as adducts 21-24 of (E,Z)- and (E,E)-1,3,5-undecatriene and methyl vinyl ketone.Another series of constituents having the norbornane skeleton represents adducts 25-32 and 33-40 of methylcyclopentadiene and octen-3-one or methyl vinyl ketone, respectively.In accordance with Alder's endo-rule the endo-isomers are preponderant in the natural as well as in the synthetic mixtures.Most of these constituents could also be identified in a lavender absolute as well as in a freshly prepared hexane extract of lavender flowers (Lavandula officinalis CHAIX).