929602-16-4

Basic information

• Product Name: Quinoline, 4-phenyl-2-[3-(trifluoromethyl)phenyl]-
• CAS NO: 929602-16-4
• Molecular Formula: C22H14F3N
• Molecular Weight: 349.355
• Mol File: 929602-16-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Quinoline, 4-phenyl-2-[3-(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 4-phenyl-2-[3-(trifluoromethyl)phenyl]-(929602-16-4)
• EPA Substance Registry System: Quinoline, 4-phenyl-2-[3-(trifluoromethyl)phenyl]-(929602-16-4)

Safety Data

• Hazardous Substances Data: 929602-16-4(Hazardous Substances Data)

Upstream product

• 454-89-7 3-Trifluoromethylbenzaldehyde 
• 64097-92-3 2-(1-phenylvinyl)aniline 
• 89424-17-9 ethyl (2-trifluoromethylbenzoyl)acetate 
• 13209-38-6 (2-aminophenyl)(phenyl)methanol 
• 454-91-1 1-(3-trifluoromethylphenyl)ethanol 
• 349-76-8 3'-(trifluoromethyl)acetophenone 
• 2835-77-0 (2-aminophenyl)(phenyl)methanone 
• 221909-97-3 3-(2-amino-phenyl)-1-(3-trifluoromethyl-phenyl)-propynone 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Substituent position engineering of diphenylquinoline-based Ir(III) complexes for efficient orange and white PhOLEDs with high color stability/low efficiency roll-off using a solution-processed emission layer

Three new heteroleptic Ir(iii) complexes o-LIrpic, m-LIrpic, and p-LIrpic (L = CF3DPQ) consisting of 2,4-diphenylquinoline (DPQ) with a -CF3 group at ortho (o)/meta (m)/para (p) positions of the metalated phenyl ring, respectively, as the main ligands were synthesized and used as emitters in phosphorescent organic light-emitting diodes (PhOLEDs). We realized that -CF3 position extremely affects the crucial photophysical and electronic properties such as emission color, photoluminescence quantum yield (PLQY) and energy levels of these Ir(iii) complexes resulting in -CF3 position-dependent performance of their PhOLEDs. To verify the effect of -CF3 group position on device performance, three other Ir(iii) complexes o-LIrtmd, m-LIrtmd, and p-LIrtmd were synthesized using the same main ligands but a different ancillary ligand. In the two series of Ir(iii) complexes, the devices with m-CF3 based complexes are outstanding in performance compared to o- or p-CF3 based ones due to the enhanced PLQY and well suppressed non-radiative deactivations by m-substitution. Finally, the single emission layer solution-processed orange and two-component white PhOLEDs fabricated using m-LIrpic as orange emitter achieved the maximum external quantum efficiency of 17.1% (43.9 cd A-1) and 21.1% (48.8 cd A-1), respectively, with highly stable color coordinates and low efficiency roll-off. This is the highest efficiency reported to date for solution-processed orange PhOLEDs using a small molecular host with easily accessible emitter.

Sustainable synthesis of quinolines (pyridines) catalyzed by a cheap metal Mn(I)-NN complex catalyst

This study represents the first example of a bidentate phosphine-free manganese(I)-NN complex catalyst for the synthesis of quinolines (pyridines) through acceptorless dehydrogenative condensation of various secondary alcohols with amino alcohols. The coupling reactions occurred at 3 mol% catalyst loading and 110°C, and tolerated diverse functional groups. Moderate to excellent yields ranging from 45% to 89% were achieved after 12 hr of reaction. The present protocol provides a concise and environmentally friendly method for the construction of heterocyclic compounds.

Iridium (III) Complexes, method for preparaion of Iridium (III) Complexes, and Organic Light-Emitting Diodes comprising thereof

The present invention relates to an iridium (III) complex which allows control of colors and shows excellent light-emitting characteristics, luminance and color purity. The present invention also relates to a method for preparing the iridium (III) complex