932-77-4

Basic information

• Product Name: 3-Bromobenzyl chloride
• Synonyms: 3-Bromobenzyl chloride 98%;1-Bromo-3-(chloromethyl)benzene;3-BROMO-ALPHA-CHLOROTOLUENE;3-BROMOBENZYL CHLORIDE;AKOS BBS-00004038;3-Bromobenzylchloride,97%;3-bromo-à-chlorotoluene;3-bromo-α-chlorotoluene
• CAS NO: 932-77-4
• Molecular Formula: C₇H₆BrCl
• Molecular Weight: 205.48
• Mol File: 932-77-4.mol
• Article Data: 6

Chemical Properties

• Melting Point: 32.5°C
• Boiling Point: 116-118 °C17 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.608 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0448mmHg at 25°C
• Refractive Index: n20/D 1.583(lit.)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• BRN: 742267
• CAS DataBase Reference: 3-Bromobenzyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromobenzyl chloride(932-77-4)
• EPA Substance Registry System: 3-Bromobenzyl chloride(932-77-4)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-28-36/37/39-45
• RIDADR: UN 3265 8/PG 2
• WGK Germany: 3
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 932-77-4(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless to light yellow liquid

InChI:InChI=1/C7H6BrCl/c8-7-3-1-2-6(4-7)5-9/h1-4H,5H2

Upstream product

• 7791-25-5 sulfuryl dichloride 
• 591-17-3 meta-bromotoluene 
• 94-36-0 dibenzoyl peroxide 
• 123-91-1 1,4-dioxane 
• 7647-01-0 hydrogenchloride 
• 456-43-9 1-bromo-3-(fluoromethyl)benzene 
• 15852-73-0 (3-Bromophenyl)methanol 
• 583-68-6 2-bromo-p-toluidine 

Downstream Products

• 856381-76-5 (3-bromo-benzyl)-o-tolyl ether 
• 6279-09-0 2-(3-bromo-benzyl)-6-methyl-phenol 
• 5422-46-8 (3-bromo-benzyl)-p-tolyl ether 
• 856191-93-0 (3-bromo-phenyl)-mesityl-methane 
• 20600-29-7 1-bromo-3-(phenoxymethyl)benzene 
• 17538-85-1 1-(3-Brombenzyl)-cyclohexanol-⁽¹⁾ 
• 3506-70-5 4-(m-Bromophenyl)-2-butanone 
• 130642-47-6 3-[2-(3-Bromo-phenyl)-ethyl]-pyridine-2-carboxylic acid tert-butylamide 
• 18880-07-4 3-bromobenzyltriphenylphosphonium chloride 
• 90433-25-3 1,1-Dimethyl-2-(m-bromophenyl)cyclopropane 
• 39959-54-1 3-bromobenzylamine hydrochloride 
• 225112-56-1 4-(3-bromo-benzylsulfanyl)-pyridine-2-carbonitrile 
• 141692-04-8 (3-bromo-benzyl)-(2,4-dibromo-phenyl)-ether 
• 859179-94-5 2,4-dibromo-6-(3-bromo-benzyl)-phenol 

Relevant articles and documents

NMP-mediated chlorination of aliphatic alcohols with aryl sulfonyl chloride for the synthesis of alkyl chlorides

NMP-mediated chlorination of aliphatic alcohols has been developed for the synthesis of alkyl chlorides. This facile, efficient and practical approach used simple and readily available aryl sulfonyl chlorides as the chlorination reagent for the construction of C–Cl bond in good to excellent yields with mild conditions and broad substrate scope.

Facile chlorination of benzyl alcohols using 1,8-diazabicyclo[5.4.0]undec- 7-ene (DBU) and sulfonyl chlorides

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Syntheses of compounds active toward glutamate receptors: II. Synthesis of spiro hydantoins of the indan series

The article describes a general procedure for synthesizing hydantoins of the indan series, which makes it possible to obtain bioisosteric analogs of 1-aminoindan-1,5-dicarboxylic acid, a group I metabotropic glutamate receptor antagonist.