93805-69-7

Basic information

• Product Name: ethyl 3-(p-isopropylphenyl)oxirane-2-carboxylate
• Synonyms: ethyl 3-(p-isopropylphenyl)oxirane-2-carboxylate;3-[4-(1-Methylethyl)phenyl]-2-oxiranecarboxylic acid ethyl ester
• CAS NO: 93805-69-7
• Molecular Formula: C₁₄H₁₈O₃
• Molecular Weight: 234.29092
• EINECS: 298-552-2
• Mol File: 93805-69-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 312.6°Cat760mmHg
• Flash Point: 127.9°C
• Appearance: /
• Density: 1.101g/cm³
• Vapor Pressure: 0.000523mmHg at 25°C
• Refractive Index: 1.523
• CAS DataBase Reference: ethyl 3-(p-isopropylphenyl)oxirane-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-(p-isopropylphenyl)oxirane-2-carboxylate(93805-69-7)
• EPA Substance Registry System: ethyl 3-(p-isopropylphenyl)oxirane-2-carboxylate(93805-69-7)

Safety Data

• Hazardous Substances Data: 93805-69-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H18O3/c1-4-16-14(15)13-12(17-13)11-7-5-10(6-8-11)9(2)3/h5-9,12-13H,4H2,1-3H3

Upstream product

• 105-39-5 chloroacetic acid ethyl ester 
• 122-03-2 (4-isopropylbenzaldehyde) 
• 128408-02-6 ethyl (E)-3-(4-isopropylphenyl)-2-propenoate 
• 74087-85-7 3,3-dimethyldioxirane 

Downstream Products

• 4395-92-0 2-[4-(1-methylethyl)phenyl]-ethanal 

Relevant articles and documents

Dioxirane Chemistry. Part 15. Rate studies on Epoxidations by Dimethyldioxirane

The relative rates of epoxidation by dimethyldioxirane, (1), of a series of 4-substituted (E)-ethyl cinnamates have been studied.The data were treated with the Hammett linear free energy relationship and give ρ = - 1.53 indicating an electrophilic O-atom transfer.Second-order rate coefficients were determined for the epoxidation of (E)-ethyl cinnamate by (1) at several temperatures and the Arrhenius factors were determined, Ea = 14.1 kcal mol-1, log (A/s-1) = 7.41.