96391-88-7

Basic information

• Product Name: ((Z)-(R)-1-Methyl-but-2-enyl)-benzene
• Synonyms: ((Z)-(R)-1-Methyl-but-2-enyl)-benzene
• CAS NO: 96391-88-7
• Molecular Weight: 146.232
• Mol File: 96391-88-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((Z)-(R)-1-Methyl-but-2-enyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-(R)-1-Methyl-but-2-enyl)-benzene(96391-88-7)
• EPA Substance Registry System: ((Z)-(R)-1-Methyl-but-2-enyl)-benzene(96391-88-7)

Safety Data

• Hazardous Substances Data: 96391-88-7(Hazardous Substances Data)

Upstream product

• 24652-50-4 (Z)-pent-3-en-2-ol 
• 100-56-1 phenylmercury(II) chloride 
• 917-54-4 methyllithium 
• 84519-63-1 (R,E)-4-phenyl-3-buten-2-yl acetate 

Relevant articles and documents

Alkylation of Allylic Derivatives. 7. Stereochemistry of Alkylation of the Isomeric trans-α,γ-Methyl(phenyl)allyl Acetates with Lithium Dialkylcuprates and Alkylcyanocuprates

Alkylation of the isomeric trans-α,γ-methyl(phenyl)allyl acetates (2-OAc and 3-OAc) with lithium dialkylcuprates or alkylcyanocuprate is stereospecific.The α-alkylation product is formed with excess inversion, and the γ-alkylation product results from excess anti bonding.Stereospecificity ranges from about 85 to 95 percent in this sterically unbiased system.