96461-81-3

Basic information

• Product Name: Benzonitrile, 4-[(4-chlorophenyl)thio]-
• CAS NO: 96461-81-3
• Molecular Formula: C13H8ClNS
• Molecular Weight: 245.732
• Mol File: 96461-81-3.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 4-[(4-chlorophenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 4-[(4-chlorophenyl)thio]-(96461-81-3)
• EPA Substance Registry System: Benzonitrile, 4-[(4-chlorophenyl)thio]-(96461-81-3)

Safety Data

• Hazardous Substances Data: 96461-81-3(Hazardous Substances Data)

Upstream product

• 18803-44-6 sodium p-chlorothiophenolate 
• 619-72-7 4-nitrobenzonitrile 
• 623-00-7 4-bromobenzenecarbonitrile 
• 106-54-7 p-Chlorothiophenol 
• 96461-98-2 4-(4-chlorophenylthio)benzoyl chloride 
• 696-63-9 4-Methoxybenzenethiol 
• 1194-02-1 4-fluorobenzonitrile 
• 141212-57-9 5-p-(p-chlorophenylsulphonyl)phenyl-3-mercapto-1,2,4-triazole 
• 623-03-0 4-Cyanochlorobenzene 
• 2863-98-1 4-hydrazinobenzonitrile hydrochloride 
• 3058-39-7 4-iodobenzonitrile 

Downstream Products

• 80988-11-0 1-(4-chlorophenylsulfonyl)-4-cyanobenzene 
• 827610-57-1 4-(4-chlorophenylsulfanyl)benzylamine 

Relevant articles and documents

Synthesis of diaryl sulfides based on copper-doped OMS-2

We describe a practical protocol for efficiently preparing diaryl sulfide compounds using Cu–OMS-2 as the catalyst. Cu–OMS-2 originates from manganese oxide octahedral molecular sieves modified with copper ions and catalyzes the C–S coupling reaction of substituted thiophenols and aryl halides. This protocol has the advantages of environmental friendliness, simple operation, high yields, good tolerance of functional groups, and the Cu–OMS-2 catalytic material can be recycled several times.

Method for synthesizing diarylthioether compound by using manganese oxide molecular sieve doped copper catalyst

The invention relates to a synthesis method of a diarylthioether compound by catalyzing with heterogeneous manganese oxide octahedral molecular sieve doped copper (Cu-OMS-2). The chemical structural formula of the compound is shown in the description, whe

Anionic Bismuth(III) chloride cluster with diselenide countercations: Application in C-S cross coupling reactions

The first weakly coordinating anion (WCA) with reactive p-block cation (rPBC) type of [(Bi4Cl16)4-{(LSeSeL)2+}2], L = 1,3-bis(2-benzhydryl-4,6-dimethylphenyl)-1H-imidazole-2(3H), ion pair is reported. The tetranuclear anionic bismuth(III) cluster shows a new type of ladder structure with two different types of Bi(III) coordination modes. In the solid state structure, the tetranuclear bismuth(III) cluster is sandwiched by two diselenide cations through hydrogen bonding interactions. Besides, this ion pair has been efficaciously employed as catalyst in C-S cross-coupling reactions under optimized reaction condition. This ion pair depicted a wide range of substrate scope with different thiols and aryl halides.