96690-02-7

Basic information

• Product Name: 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose
• Synonyms: 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose
• CAS NO: 96690-02-7
• Molecular Weight: 428.601
• Mol File: 96690-02-7.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose(96690-02-7)
• EPA Substance Registry System: 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose(96690-02-7)

Safety Data

• Hazardous Substances Data: 96690-02-7(Hazardous Substances Data)

Upstream product

• 532-20-7 D-Ribose 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 50-69-1 D-ribose 
• 67814-68-0 2,3-O-isopropylidene-β-D-ribofuranose 
• 67814-68-0 2,3-O-isopropylidene-D-ribofuranose 
• 10257-32-6 D-ribose 
• 13199-25-2 2,3-O-Isopropylidene-D-ribose 

Downstream Products

• 915694-38-1 (3aR,3bR,4aS,5S,5aS)-3b-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethylhexahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3]dioxol-5-ol 
• 82950-51-4 3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-α-D-ribofuranosyl)prop-1-ene 
• 130222-85-4 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-D-ribitol 
• 478367-12-3 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-ribofuranosyl trichloroacetamidate 
• 476311-58-7 2,5-anhydro-6-O-[tert-butyl(diphenyl)silyl]-3,4-O-isopropylidene-D-altritol 
• 557794-46-4 5-(tert-butyldiphenylsilyl)-1-deoxy-1-hydroxyamino-2,3-O-isopropylidene-β-D-ribo-1,4-pentofuranose 

Relevant articles and documents

Stereoselective synthesis of selenium-containing glycoconjugates via the mitsunobu reaction

A simple and efficient route for the synthesis of new glycoconjugates has been developed. The approach acts as a model for a mini-library of compounds with a deoxy-selenosugar core joined to a polyphenolic moiety with well-known antioxidant properties. An unexpected stereocontrol detected in the Mitsunobu key reaction led to the most attractive product showing a natural Dconfiguration. Thus, we were able to obtain the target molecules from the commercially available D-ribose via a shorter and convenient sequence of reactions.

Highly regioselective and stereoselective synthesis of C-Aryl glycosidesvianickel-catalyzedortho-C-H glycosylation of 8-aminoquinoline benzamides

C-Aryl glycosides are of high value as drug candidates. Here a novel and cost-effective nickel catalyzedortho-CAr-H glycosylation reaction with high regioselectivity and excellent α-selectivity is described. This method shows great functional group compatibility with various glycosides, showing its synthetic potential. Mechanistic studies indicate that C-H activation could be the rate-determining step.

POLYMORPHIC COMPOUNDS AND USES THEREOF

The present invention provides compounds and methods of use thereof for treatment of certain disorders and conditions, for example brain injuries such as stroke or traumatic brain injuries.