98678-39-8

Basic information

• Product Name: methyl 3-(methoxycarbonyl)-1-phenyl-1,2,3,4-tetrahydro-naphthalene-2-carboxylate
• Synonyms: methyl 3-(methoxycarbonyl)-1-phenyl-1,2,3,4-tetrahydro-naphthalene-2-carboxylate
• CAS NO: 98678-39-8
• Molecular Weight: 324.376
• Mol File: 98678-39-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 3-(methoxycarbonyl)-1-phenyl-1,2,3,4-tetrahydro-naphthalene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(methoxycarbonyl)-1-phenyl-1,2,3,4-tetrahydro-naphthalene-2-carboxylate(98678-39-8)
• EPA Substance Registry System: methyl 3-(methoxycarbonyl)-1-phenyl-1,2,3,4-tetrahydro-naphthalene-2-carboxylate(98678-39-8)

Safety Data

• Hazardous Substances Data: 98678-39-8(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 67-56-1 methanol 
• 105580-92-5 (+/-)-1r-phenyl-1,2,3,4-tetrahydro-naphthalene-dicarboxylic acid-(2t.3t) 
• 95539-08-5 4-Phenyl-1,4-dihydro-benzo[d][1,2]oxathiine 3-oxide 
• 624-48-6 dimethyl cis-but-2-ene-1,4-dioate 
• 95539-05-2 1-hydroxy-4 phenyl-1,3-dihydrobenzothiophene-2,2-dioxide 
• 98678-45-6 trans 2,3-bis(methoxycarbonyl)-1-phenyl-1,2-dihydronaphthalene 
• 105580-92-5 (+/-)-1r-phenyl-1,2,3,4-tetrahydro-naphthalene-dicarboxylic acid-(2c.3c) 
• 32832-95-4 2-benzylbenzaldehyde 

Relevant articles and documents

Electrochemical generation and reaction of o-quinodimethanes from {[[2-(2,2-dibutyl-2-stannahexyl)phenyl]-methyl]thio} benzenes

(equation presented) The anodic oxidation of {[[2-(2,2-dibutyl-2-stannahexyl)phenyl]methyl]thio}benzenes gave o-quinodimethanes which were trapped in situ by dienophiles to give the corresponding cycloadducts in excellent yields. The electron transfer and succeeding 1,4-elimination reaction was efficiently completed in a solution of lithium perchlorate/nitromethane in the presence of acetic acid. The reaction progress was quantitatively controlled by the passage of charge. By using this new method, an aryltetralin lignan skeleton was also synthesized.

Stereoselectivity in the Diels-Alder Reaction of Phenyl- and Oxy-Substituted o-Quinodimethanes

Phenyl-, methoxy-, and acetoxy-substituted o-quinodimethanes (o-QDM) have been added to dimethyl fumarate and maleate to determine the stereoselectivity of the addition reaction.The o-QDM's were generated from the corresponding 1,3-dihydrobenzothiophen