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N-Vinylcaprolactam msds

N-Vinylcaprolactam msds information
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    The material safety data sheet (MSDS) of N-Vinylcaprolactam is one important component for product N-Vinylcaprolactam's stewardship and workplace safety. You could refer to the N-Vinylcaprolactam manufacturer for more detailed product information. And N-Vinylcaprolactam msds below is provided by Nanjing Aily Biotechnology Co., Ltd, one specialized Ferrocene carboxylic acid supplier in China.

    1. Product and Company Identification


     Molecular formula: CH(2)CHNCOC(5)H(10)
    Chemical family: lactam
    Synonyms: N-VINYLCAPROLACTAM

    2. Hazards Identification

    Emergency overview

    WARNING: Causes eye irritation.
    CONTAINS MATERIAL WHICH MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA.
    CONTAINS MATERIAL WHICH MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA.
    MAY CAUSE RESPIRATORY TRACT IRRITATION.
    Use with local exhaust ventilation.
    Wear a NIOSH-certified (or equivalent) particulate respirator.
    Wear NIOSH-certified chemical goggles.
    Wear protective clothing.
    State of matter: solid
    Colour: colourless to yellow
    Odour: characteristic, mild

    Potential health effects

    Primary routes of exposure:
    Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for
    gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

    Acute toxicity:
    Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Inhalation-risk test (IRT):
    No mortality within 8 hours as shown in animal studies. The inhalation of a highly saturated vapor-air mixture
    represents no acute hazard.

    Irritation / corrosion:
    Eye contact causes irritation. Not irritating to the skin. Causes temporary irritation of the respiratory tract.

    Assessment other acute effects:
    Causes temporary irritation of the respiratory tract.

    Chronic toxicity:

    Carcinogenicity: No data available concerning carcinogenic effects. However, because of the chemical
    structure, a carcinogenic potential cannot be excluded.
    Repeated dose toxicity: The substance may cause damage to the liver after repeated inhalation. The
    substance may cause damage to the upper respiratory tract even after repeated inhalation, as shown in animal
    studies.
    Reproductive toxicity: No data available concerning reproduction toxicity.
    Teratogenicity: No data available concerning teratogenic effects.
    Genotoxicity: No mutagenic effect was found in various tests with bacteria and mammalian cell culture.

    Medical conditions aggravated by overexposure:

    Data available do not indicate that there are medical conditions that are generally recognized as being
    aggravated by exposure to this substance/product. See MSDS section 11 - Toxicological information.

    Signs and symptoms of overexposure:
    The most important known symptoms and effects are described in the labelling (see section 2) and/or in section

    Potential environmental effects


    Aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations.

    3. Composition / Information on Ingredients

    CAS Number: 2235-00-9
    Content (W/W)
    Chemical name: vinylcaprolactam

    4. First-Aid Measures

    General advice: Remove contaminated clothing.

    If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. If breathing difficulties develop, aid in breathing and seek immediate medical attention.

    If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention.

    If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Seek medical attention.

    If swallowed: Rinse mouth and then drink plenty of water. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Seek medical attention.
    Treatment: Treat according to symptoms (decontamination, vital functions), no known

    5. Fire-Fighting Measures

    Flash point: 114 °C
    Autoignition: 220 °C
    Lower explosion limit: 1.4 %(V)
    Upper explosion limit: 6.5 %(V)
    Self-ignition temperature: not applicable (Based on its structural properties the product is not classified as self-igniting.)

    Suitable extinguishing media: carbon dioxide, dry powder, water spray, foam

    Hazards during fire-fighting: nitrogen oxides, carbon oxides The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

    Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

    Further information: If exposed to fire, keep containers cool by spraying with water.

    6. Accidental release measures

    Personal precautions:
    Handle in accordance with good industrial hygiene and safety practice.

    Environmental precautions:
    This product is regulated by CERCLA ('Superfund').

    Cleanup:
    Spills should be contained, solidified, and placed in suitable containers for disposal.

    7. Handling and Storage

    Handling
    General advice: Ensure thorough ventilation of stores and work areas.

    Protection against fire and explosion: No explosion proofing necessary.

    Storage
    General advice: Keep container tightly closed in a cool, well-ventilated place. Avoid extreme heat.

    Storage stability:
    Storage temperature: 25 °C
    Storage duration: 24 Months
    The product is stabilized, the shelf life should be noted. From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

    Temperature tolerance
    Protect from temperatures above: 40 °C
    Properties of the product change irreversibly on exceeding the limit temperature.

    8. Exposure Controls and Personal Protection

    Advice on system design: Provide local exhaust ventilation to maintain recommended P.E.L.

    Personal protective equipment
    Respiratory protection: Wear the following respiratory protection if controls are not feasible: Wear a NIOSH-certified (or equivalent)particulate respirator. For emergency or non-routine, high exposure situations, use a NIOSH-certified full facepiece pressure demand self contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Observe OSHA regulations for respirator use (29 CFR 1910.134).

    Hand protection: Chemical resistant protective gloves, butyl rubber

    Eye protection: Tightly fitting safety goggles (chemical goggles).

    Body protection: Body protection must be chosen based on level of activity and exposure.

    General safety and hygiene measures: Eye wash fountains and safety showers must be easily accessible. Wear protective clothing as necessary to minimize contact. Avoid contact with the skin, eyes and clothing. Avoid prolonged and/or repeated contact with the skin. Handle in accordance with good industrial hygiene and safety practice. Wash soiled clothing immediately.

    9. Physical and Chemical Properties

    Form: solid
    Odour: characteristic, mild
    Colour: colourless to yellow

    10. Stability and Reactivity

    Conditions to avoid: Avoid prolonged storage. Avoid heat.

    Substances to avoid: strong oxidizing agents, bases

    Hazardous reactions: The product is stabilized against spontaneous polymerization prior to despatch. Polymerization coupled with heat formation. The product can polymerize if the shelf life or storage temperature are greatly exceeded. Reacts with acids. Reacts with peroxides and other radical components.

    Decomposition products: carbon monoxide, carbon dioxide Hazardous decomposition products: carbon monoxide, carbon dioxide

    Thermal decomposition:
    135 °C (DSC (DIN 51007))
    First exothermic reaction at indicated temperature.
    210 °C (DSC (DIN 51007))
    Risk of exothermic self-accelerating decomposition above the indicated temperature.

    Corrosion to metals: No corrosive effect on metal.

    Oxidizing properties: Based on its structural properties the product is not classified as oxidizing.

    11. Toxicological information

    Acute toxicity

    Oral:
    Type of value: LD50
    Species: rat
    Value: approx. 1,400 mg/kg (BASF-Test)

    Information on: caprolactam
    Type of value: LD50
    Species: rat (female)
    Value: 1,475 mg/kg (Directive 84/449/EEC, B.1)

    Inhalation:
    Type of value: LC0
    Species: rat
    Value: (IRT)
    Exposure time: 8 h
    Inhalation-risk test (IRT): No mortality within 8 hours as shown in animal studies. The inhalation of a highly saturated vapor-air mixture represents no acute hazard.

    Information on: caprolactam
    Type of value: LC50
    Species: rat (male/female)
    Value: approx. 8.16 mg/l (BASF-Test)
    Exposure time: 4 h
    An aerosol with respiratory particles was tested.

    Dermal:
    Type of value: LD50
    Species: rat
    Value: > 2,000 mg/kg (BASF-Test)

    Information on: caprolactam
    Type of value: LD50
    Species: rat (male/female)
    Value: > 2,000 mg/kg (Directive 92/69/EEC, B.3)

    Irritation / corrosion

    Skin:
    Species: rabbit
    Result: non-irritant
    Method: BASF-Test

    Eye:
    Species: rabbit
    Result: Irritant.
    Method: BASF-Test

    Sensitization:
    Mouse Local Lymph Node Assay (LLNA)
    Species: mouse
    Result: sensitizing
    Method: OECD Guideline 429

    Information on: caprolactam
    modified Buehler test
    Species: guinea pig
    Result: Non-sensitizing.
    Method: OECD Guideline 406

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