On the temperature dependence of the two-dimensional condensation of 5-IODOCYTOSINE (cas 1122-44-7) at the mercury/electrolyte interface
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Add time:09/26/2019 Source:sciencedirect.com
By way of capacity-potential curves of 5-IODOCYTOSINE (cas 1122-44-7) in th epotential range of the cathodic pit edge, the dependence of the critical degree of coverage of a two-dimensional condensed adsorption film on temperature was investigated. The Frumkin interaction coefficient determined from the critical degree of coverage does not depend linearly on the reciprocal temperature as would be the case in correspondence to the temperature dependence of the pit width. This contradiction does not occur if the interaction coefficient is determined from the critical degree of coverage on the basis of the lattice gas model, i.e. if the short-range order of adsorbed molecules is taken into consideration.
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