Total Synthesis of (+/-)-Cyclolaurene, (+/-)-Epicyclolaurene and (+/-)-β-Cuparenone
The first total synthesis of (+/-)-cyclolaurene (1) and (+/-)-epicyclolaurene (5), and a new route to (+/-)-β-cuparenone (4) are reported.Thus, orthoester Claisen rearrangement of the cinnamyl alcohol 8 furnished the ene-ester 10.Anhydrous CuSO4 catalysed
Srikrishna, Adusumilli,Krishnan, Kathiresan
p. 3429 - 3436
(2007/10/02)
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