- Unexpected reaction of N,N-dichloroarenesulfonamides with divinyl sulfide: Formation of N-[2-chloro- and N-[2,2-dichloro-1-(arylsulfonylamino)ethyl] arenesulfonamides
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Reaction of N,N-dichloroarenesulfonamides with divinyl sulfide was accompanied by cleavage of divinyl sulfide moiety and resulted in unexpected N-[2-chloro- and N-[2,2-dichloro-1-(arylsulfonylamino)ethyl]arenesulfonamides as final products. Possible react
- Rozentsveig, Igor B.,Rozentsveig, Gulnur N.,Levkovskaya, Galina G.,Amosova, Svetlana V.,Potapov, Vladimir A.,Chernyshev, Kirill A.,Tretyakov, Eugene V.,Romanenko, Galina V.
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experimental part
p. 181 - 192
(2011/12/05)
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- N,N-DICHLOROARENESULFONAMIDES IN REACTION WITH 1,2-DICHLOROETHYLENE
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The reaction of N,N-dichloroarenesulfonamides with cis- and trans-1,2-dichloroethylene under the conditions of free-radical initiation lead to the formation of the N-arylsulfonylimines of dichloroacetaldehyde and the products from their further transformation, i.e., 2,2-dichloro-1,1-di(arylsulfonylamino)ethanes.The arylsulfonylimines of chloral, arenesulfonamides, trichloroethylene, and the products from chlorination of 1,2-dichloroethylene are formed as side products.
- Mirskova, A. N.,Drozdova, T. I.,Levkovskaya, G. G.,Kalikhman, I. D.,Voronkov, M. G.
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p. 1129 - 1135
(2007/10/02)
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