145586-17-0

Basic information

• Product Name: H-D-LYS(Z)-OME HCL
• Synonyms: D-LYSINE(Z)-OME HCL;N-EPSILON-Z-D-LYSINE METHYL ESTER HYDROCHLORIDE;N-EPSILON-BENZYLOXYCARBONYL-D-LYSINE METHYL ESTER HYDROCHLORIDE SALT;N-EPSILON-CARBOBENZOXY-D-LYSINE METHYL ESTER HYDROCHLORIDE;NEPSILON-Benzyloxycarbonyl-D-lysine methyl ester hydrochloride;Methyl N~6~-[(benzyloxy)carbonyl]lysinate hydrochloride;D-Lysine, N6-[(phenylMethoxy)carbonyl]-, Methyl ester;N6-[(Phenylmethoxy)carbonyl]-D-lysine methyl ester
• CAS NO: 145586-17-0
• Molecular Formula: C₁₅H₂₂N₂O₄
• Molecular Weight: 330.81
• EINECS: 248-715-9
• Product Categories: Amino Acid Derivatives;Amino Acids
• Mol File: 145586-17-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 470.6°C at 760 mmHg
• Flash Point: 238.4°C
• Appearance: /
• Vapor Pressure: 2.96E-09mmHg at 25°C
• Storage Temp.: 2-8°C
• CAS DataBase Reference: H-D-LYS(Z)-OME HCL(CAS DataBase Reference)
• NIST Chemistry Reference: H-D-LYS(Z)-OME HCL(145586-17-0)
• EPA Substance Registry System: H-D-LYS(Z)-OME HCL(145586-17-0)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 145586-17-0(Hazardous Substances Data)

Usage

Chemical Properties

White powder

InChI:InChI=1/C15H22N2O4.ClH/c1-20-14(18)13(16)9-5-6-10-17-15(19)21-11-12-7-3-2-4-8-12;/h2-4,7-8,13H,5-6,9-11,16H2,1H3,(H,17,19);1H/t13-;/m0./s1

Upstream product

• 34404-32-5 (R)-2-amino-6-(((benzyloxy)carbonyl)amino)hexanoic acid 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 107964-48-7 N(α)-Palmitoyl-N(ε)-benzyloxycarbonyl-D-lysin-methlester 
• 101121-14-6 N(α)-Palmitoyl-N(ε)-benzyloxycarbonyl-D-lysin-hydrazid 
• 96384-52-0 N^α-palmitoyl-N-benzyloxycarbonyl-D-lysyl-N^ε-benzyloxycarbonyl-D-lysine etyl ester 
• 95691-44-4 N^α-tert-butyloxycarbonyl-L-β-(uracilyl-N¹)-α-alanyl-N^ε-benzyloxycarbonyl-D-lysine 
• 246869-90-9 (R)-6-Benzyloxycarbonylamino-2-{[(2S,3R)-1-(3,3-diphenyl-propionyl)-3-phenyl-pyrrolidine-2-carbonyl]-amino}-hexanoic acid methyl ester 
• 246869-86-3 (R)-6-Benzyloxycarbonylamino-2-{[(2R,3S)-1-(3,3-diphenyl-propionyl)-3-phenyl-pyrrolidine-2-carbonyl]-amino}-hexanoic acid methyl ester 
• 246869-82-9 (R)-6-Benzyloxycarbonylamino-2-{[(2S,3S)-1-(3,3-diphenyl-propionyl)-3-phenyl-pyrrolidine-2-carbonyl]-amino}-hexanoic acid methyl ester 
• 246869-78-3 (R)-6-Benzyloxycarbonylamino-2-{[(2R,3R)-1-(3,3-diphenyl-propionyl)-3-phenyl-pyrrolidine-2-carbonyl]-amino}-hexanoic acid methyl ester 
• 95691-43-3 N^α-tert-butyloxycarbonyl-L-β-(uracilyl-N¹)-α-alanyl-N^ε-benzyloxycarbonyl-D-lysine methyl ester 

Relevant articles and documents

Homophymamide A, Heterodetic Cyclic Tetrapeptide from a Homophymia sp. Marine Sponge: A Cautionary Note on Configurational Assignment of Peptides That Contain a Ureido Linkage

A previously unreported heterodetic cyclic peptide, homophymamide A (1), was isolated from a Homophymia sp. marine sponge. The structure of homophymamide A was determined to be a lower homologue of anabaenopeptins by spectroscopic analysis, chemical degradation, and chemical synthesis. Analysis of the acidic hydrolysate showed that the racemization of Lys took place, leading us to pose a cautionary note on the configurational assignment of peptides that contain a ureido bond.