61358-25-6

Basic information

• Product Name: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
• Synonyms: BIS(4-TERT-BUTYLPHENYL)IODONIUM HEXAFLUOROPHOSPHATE; Iodonium bis[4-(1,1-dimethylethyl)phenyl] Hexafluorophospha;Bis(4-t-butyl phenyl)iodonium hexafluorophosphate;HRcure-9388;Bis(4-(tert-butyl);iodonium hexafluorophosphate(V);bis(4-tert-butylphenyl)iodanium:hexafluorophosphate;iodonium salt
• CAS NO: 61358-25-6
• Molecular Formula: C₂₀H₂₆I*F₆P
• Molecular Weight: 538.29
• Product Categories: Diphenyliodonium Compounds;Functional Materials;Iodonium Sulfonium & Oxonium Compounds;Photopolymerization Initiators;Photoinitiator
• Mol File: 61358-25-6.mol
• Article Data: 1

Chemical Properties

• Melting Point: 174 °C
• Appearance: /
• Density: 1.57g/cm3 at 21℃
• Vapor Pressure: 0Pa at 25℃
• Solubility: soluble in Ethanol
• BRN: 5721061
• CAS DataBase Reference: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate(61358-25-6)
• EPA Substance Registry System: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate(61358-25-6)

Safety Data

• Hazard Codes: C
• Statements: 36/37/38-34
• Safety Statements: 26-36-45-36/37/39
• RIDADR: UN 1759 8 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 61358-25-6(Hazardous Substances Data)

Usage

Description

Bis(4-tert-butylphenyl)iodonium hexafluorophosphate, also known as a phosphonium salt, is an organic compound that serves as a catalyst in various chemical reactions. It is characterized by its ability to facilitate the process of photoinduced thermal polymerization, making it a valuable component in the field of materials science and polymer chemistry.

Uses

Used in Polymer Chemistry:
Bis(4-tert-butylphenyl)iodonium hexafluorophosphate is used as a catalyst for photoinduced thermal polymerization reactions. Its application in this field is due to its ability to promote the polymerization process, leading to the formation of polymers with desired properties and characteristics. This makes it a crucial component in the synthesis of various polymers, including those used in plastics, coatings, and adhesives.
Used in Materials Science:
In the field of materials science, Bis(4-tert-butylphenyl)iodonium hexafluorophosphate is used as a catalyst to enhance the properties of materials through controlled polymerization. Its role in this industry is to improve the mechanical, thermal, and chemical properties of the resulting materials, making them more suitable for specific applications such as electronics, automotive, and aerospace industries.
Used in Pharmaceutical Applications:
Although not explicitly mentioned in the provided materials, Bis(4-tert-butylphenyl)iodonium hexafluorophosphate may also find applications in the pharmaceutical industry, particularly in the development of new drugs and drug delivery systems. Its unique chemical properties could potentially be harnessed to improve the efficacy and delivery of therapeutic agents, contributing to advancements in drug design and development.

InChI:InChI=1/C20H26I.F6P/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;1-7(2,3,4,5)6/h7-14H,1-6H3;/q+1;-1

Upstream product

• 253185-03-4 tert-butylbenzene 

Downstream Products

• 253185-03-4 tert-butylbenzene 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 358-63-4 tris(2,2,2-trifluoroethyl) phosphate 
• 1428647-08-8 bis(2,2,2-trifluoroethyl) tert-butylphenylphosphonate 
• 172422-37-6 Phenyl-phosphonic acid bis-(2,2,2-trifluoro-ethyl) ester 
• 1451064-02-0 ethyl 2-(4-tert-butylbenzyl) acrylate 
• 160001-85-4 1-(tert-butyl)-4-(trifluoromethyl)benzene 
• 23055-77-8 4'-chloro-4-bromo-biphenyl 
• 462-06-6 fluorobenzene 
• 591-50-4 iodobenzene 
• 22904-43-4 4-tert-Butyl-phenylradikal 
• 100-66-3 methoxybenzene 
• 35779-04-5 tert-Butylphenyliodoniumradikalkation 

Relevant articles and documents

Photoredox-Catalyzed Cascade Reactions Involving Aryl Radical: Total Synthesis of (±)-Norascyronone A and (±)-Eudesmol

Herein, we have developed two types of photoredox-catalyzed cascade reactions using diaryliodonium salts for the concise synthesis of norascyronone A and β-eudesmol. A rationally designed photoredox-catalyzed arylation/cyclization/Friedel-Crafts cascade reaction of enone was exploited to generate the norascyronone polycyclic skeleton. A visible-light-induced radical cyclization/acyloxy-migration reaction was explored to forge the decalin skeleton of eudesmol, and mechanistic studies indicated the reaction was initiated by one-electron oxidation of the enol ester.