95091-93-3 Usage
Description
1-(3-BROMOPROPYL)-2,2,5,5-TETRAMETHYL-1-AZA-2,5-DISILACYCLOPENTANE is a chemical compound that serves as an intermediate in the synthesis of various materials, particularly in the production of block copolymers.
Uses
Used in Polymer Synthesis:
1-(3-BROMOPROPYL)-2,2,5,5-TETRAMETHYL-1-AZA-2,5-DISILACYCLOPENTANE is used as a monomer or building block for the synthesis of PFS-b-PZLys block copolymers, where PFS stands for Polyferrocenylsilane and PZLys represents Poly(epsilon-benzyloxycarbonyl-L-lysine). 1-(3-BROMOPROPYL)-2,2,5,5-TETRAMETHYL-1-AZA-2,5-DISILACYCLOPENTANE plays a crucial role in the development of new materials with unique properties and potential applications in various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 95091-93-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,5,0,9 and 1 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 95091-93:
(7*9)+(6*5)+(5*0)+(4*9)+(3*1)+(2*9)+(1*3)=153
153 % 10 = 3
So 95091-93-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H22BrNSi2/c1-12(2)8-9-13(3,4)11(12)7-5-6-10/h5-9H2,1-4H3
95091-93-3Relevant articles and documents
Allene C(sp2)-H Activation and Alkenylation Catalyzed by Palladium
Aouane, Fran?oise A.,Baik, Mu-Hyun,Carreira, Erick M.,Schreib, Benedikt S.,Son, Mina
supporting information, p. 21705 - 21712 (2022/01/03)
The selective transition-metal-mediated activation of C(sp2)-H bonds of allenes is a formidable challenge because of the competitive, intrinsic reactivity of cumulated double bonds. Herein, we report a Pd-catalyzed C-H alkenylation of electronically unbiased allenes, affording penta-1,2,4-triene products in up to 94% yield. A picolinamide directing group enables the formation of putative allenyl-palladacycles, which subsequently participate in a turnover-limiting Heck-type reaction with electron-deficient alkene coupling partners. This mechanistic proposal is consistent with experimental and computational investigations. Additionally, we report for the first time the use of picolinamide N,O-acetals as readily removable auxiliaries for C-H activation reactions, allowing the efficient alkenylation of allenyl carbinol derivatives. Successful removal of the directing groups without affecting the reactive penta-1,2,4-triene substructure of the products is demonstrated.