Journal of Organic Chemistry p. 5078 - 5084 (2013)
Update date:2022-08-04
Topics:
Li, Xiao-Jian
Zhang, Jin-Ling
Geng, Yu
Jin, Zhong
Nickel-catalyzed Suzuki-Miyaura coupling of heteroaryl ethers with arylboronic acids was described. Selective activation of the phenol C-O bonds was achieved by converting them into the corresponding aryl 2,4-dimethoxy-1,3,5- triazine-6-yl ethers, in which aryl C-O bond could be selectively cleaved with inexpensive, air-stable NiCl2(dppf) as a catalyst. Coupling of these readily accessible heteroaryl ethers proved tolerant of extensive functional groups.
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