Catalysis Communications p. 38 - 42 (2017)
Update date:2022-08-05
Topics:
Zhou, Xiao
Wei, Xian-Yong
Liu, Zhong-Qiu
Lv, Jing-Hui
Wang, Yue-Lun
Li, Zhan-Ku
Zong, Zhi-Min
An active bifunctional nickel catalyst was prepared by decomposing Ni(CO)4 to highly dispersed metallic Ni onto Hβ zeolite and first applied in hydroconverting benzyloxybenzene (BOB), which was used as a lignin-related model compound. Ni/Hβ proved to be effective for converting BOB to bicyclic cyclanes (BCCs) via Calk–O bond cleavage induced by H+ addition, benzylium addition to 2- and 4-positions in phenol, hydrogenation of benzene ring, dehydration, and H? abstraction. Compared to one-step conversion, the total BCC selectivity (TBCCS) significantly increases from catalytic hydroconversion of catalytically converted BOB by pretreatment under pressurized N2.
View MoreContact:+86-10-59484199
Address:No.58-A1026 Liangguan Street
DANYANG ZHONGTAI TRADE CO .,LTD.
Contact:0086-511-86985511
Address:No.25,Dongfang Rd., Danyang City.Jiangsu P.R.China
TIANJIN BAOLIRUITE CHEMICALS CO.,LTD
Contact:+86-022-58652605
Address:NO.60,xiqing high-end metal products industrial zone, Tianjin, China.
Wuhan Benjamin Pharmaceutical Chemical Co.,Ltd
Contact:86-27-52341789
Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.
Contact:86-10-87645213
Address:Sifangjing Garden Fengtai District Beijing
Doi:10.1021/jo01342a053
(1966)Doi:10.1021/ma034038i
(2003)Doi:10.1021/ma0507490
(2005)Doi:10.1021/acs.orglett.0c02746
(2020)Doi:10.1002/(SICI)1099-0690(199806)1998:6<1123::AID-EJOC1123>3.0.CO;2-Y
(1998)Doi:10.1016/S0040-4020(01)93143-6
(1970)