Chemistry of Natural Compounds p. 482 - 487 (1981)
Update date:2022-08-04
Topics:
Dzhemilev, U. M.
Fekhretdinov, R. N.
Telin, A. G.
Tolstikov, G. A.
Amirkhanov, D. V.
Krivonogov, V. P.
A fairly simple and original one-stage method of obtaining optically active attractants of Porthetria dispar-(+)-and (-)-2-methyl-Z- and E-7,8-epoxyoctadecanes has been developed.The synthesis is based on the epoxidation of 2-methyloctadec-Z- and -E-7-enes by chiral peroxide complexes of molybdenum of the type of MoO5-L* in an organic solvent at room temperature.Derivatives of tartaric, lactic, β-aminopropionic, and aspartic acids have been used as the chiral ligands (L*).
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