Bulletin of the Chemical Society of Japan p. 3323 - 3325 (1986)
Update date:2022-08-17
Topics:
Shibata, Katsuyoshi
Saito, Yoshiyuki
Urano, Katsuyoshi
Matsui, Masaki
The reactions of Schiff bases such as N-benzylideneanilines with superoxide ion in acetonitrile under mild conditions gave the cyanomethyl adducts, 3-arylamino-3-arylpropionitriles, as the main products in relatively good yields.In the case of N-(4-nitrobenzylidene)aniline, the adduct was further oxidized to β-anilino-4-nitrocinnamonitrile.No oxidative products such as amides were obtained except in the reactions of N-(4-chloro-and 4-nitrobenzylidene)aniline.
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