Tetrahedron Letters p. 9023 - 9026 (1997)
Update date:2022-08-15
Topics:
Kaneda, Kiyotomi
Fujie, Yoko
Ebitani, Kohki
A giant Pd cluster, Pd561phen60(OAc)180 has high catalytic activity for the selective oxidations of various primary allylic alcohols to the corresponding α,β-unsaturated aldehydes in the presence of molecular oxygen under mild reaction conditions. A Pd cluster anchored on TiO2, also catalyzes the above oxidations; the heterogeneous Pd561 cluster catalyst is easily separated from the reaction mixture and is reusable.
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