New Journal of Chemistry p. 5410 - 5418 (2020)
Update date:2022-08-17
Topics:
Kurbah, Sunshine Dominic
Lal, Ram A.
We report the synthesis and characterization of a new self-assembled VO2-L metallogel. Gel formation was investigated by dissolving VO2-L in various solvents and it was found that water/methanol (1?:?9 (v/v) ratio) induces gel formation. The single crystal X-ray structure of the VO2-L metallogel exhibits C-H?O and N-H?O hydrogen bonding interactions and pi-pi stacking. The VO2-L xerogel obtained after removing the solvents was found to exhibit outstanding performance in catalysis. Bromoperoxidase-like activity of the VO2-L metallogel was also reported. The present catalytic studies are simple and proceed under mild conditions.
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