Journal of Pharmaceutical Sciences p. 479 - 482 (1992)
Update date:2022-08-18
Topics:
Bosca
Martinez-Manez
Miranda
Primo
Soto
Vano
The decarboxylation of naproxen (1H) and its salt (1-) was achieved by means of chemical [Ce(IV) or S2O8/2-] and electrochemical oxidation. The product patterns were compatible with mechanisms involving single-electron transfer from the pl-system or the carboxylate moiety. The results are discussed in connection with the involvement of electron-transfer processes in the reported phototoxicity of naproxen.
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