Synthetic Communications p. 1747 - 1758 (2016)
Update date:2022-08-10
Topics:
Wu, Jianglong
Liu, Yan
Ma, Xiaowei
Liu, Ping
Gu, Chengzhi
Dai, Bin
We report a simple, yet efficient metal-free oxidation of secondary benzylic alcohols in the presence of t-butyl hydroperoxide (70% TBHP) with high yields of up to 98%. This type of reaction can be carried out using a wide variety of substrates, requires no other organic solvent, and proves to be tolerant toward a variety of different functional groups.
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