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of the electron binding energy of the different valence
states on the coordination environment of rhodium.
60 We observed that the “aging process” in the crystals occurs
spontaneously over time. In general, Rh(I) species are very
reactive and can be oxidized to Rh(III) under ambient con-
ditions. The X-ray diffraction studies were performed on
“aged” samples Rh/PCN-222(a) and Rh/NU-1102(a).
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O. Fuhr, K. V. Kovtunov, A. Fedorov, D. Fenske, 61 Assuming that the metal oxides ZrO
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2 2 3
and Rh O are the
7
62 The observed induction period can be significantly
reduced in the presence of water. See section S5.5 in the
ESI.†
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9058 | Dalton Trans., 2021, 50, 9051–9058
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