Carbohydrate Research p. 19 - 24 (1986)
Update date:2022-08-11
Topics:
Tiwari, Kamal N.
Dhawale, Motiram R.
Szarek, Walter A.
Hay, George W.
Kropinski, Andrew M. B.
2-Deoxy-D-arabino-hexitol (6) was obtained by borohydride reduction of 2-deoxy-D-arabino-hexose (5).The synthesis of 5, starting from 2,3:4,5-di-O-isopropylidene-D-arabinitol (1), was achieved by one-carbon chain-elongation involving formylation of the Grignard reagent derived from 1-bromo-1-deoxy-2,3:4,5-di-O-isopropylidene-D-arabinitol (2), using lithium formate, followed by hydrolytic removal of the isopropylidene groups.Immobilized cells of Gluconobacter oxydans (ATCC) 15178) selectively oxidized 6 to give 5-deoxy-D-threo-hexulose (7) in 65percent yield (-9percent overall yield from 1).
View MoreContact:86-931-8272767
Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Changde Yungang Biotechnology Co., Ltd
website:http://www.cdyg.com
Contact:+86-736-7391178
Address:Qiaonan Industrial Park, Changde City, Hunan Province
AllyChem Co., Ltd., Dalian, China(BBChem)
Contact:+86-411-62313318/62313328
Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Weihao Chemtech (ChangZhou) Co., Ltd.
Contact:051989185693
Address:NO 217 huangshan Rd ,Changzhou
Doi:10.1002/adsc.200800522
(2009)Doi:10.1039/c39830000520
(1983)Doi:10.1021/acs.inorgchem.9b00679
(2019)Doi:10.1021/ja00864a033
(1962)Doi:10.1063/1.1749890
(1936)Doi:10.1021/ol990673q
(1999)