Synthetic Communications p. 2533 - 2537 (1999)
Update date:2022-08-11
Topics:
Khoo, Lian Ee
3-Aminocoumarin and its derivatives are prepared by a thermal (150- 170°C) conversion reaction on the corresponding ethyl N-2- hydroxyarylideneglycinates,[2-HOC6H3(X)CH=NCH2CO2C2Hs; X = H, 5-Br, 5- OH, 5-NO2, 3-OMe, 4-OMe, and 5,6-benzo], which are synthesized by condensing ethyl glycinate hydrochloride with substituted salicylaldehyde.
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